288403

反-二氯双(三苯基膦)铂(II)

• 别名: trans-Bis(triphenylphosphine)platinum dichloride
• 线性分子式: [(C₆H₅)₃P]₂PtCl₂
• CAS号: 14056-88-3
• 分子量: 790.56
• MDL编号: MFCD00010825
• UNSPSC代码: 12161600
• PubChem化学物质编号: 24857337
• NACRES: NA.22

属性

• 反应适用性: core: platinum; reagent type: catalyst
• SMILES字符串: Cl[Pt]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
• InChI: 1S/2C18H15P.2ClH.Pt/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
• InChI key: XAFJSPPHVXDRIE-UHFFFAOYSA-L

说明

应用

Catalyst for:

• Preparation of soluble polymers of monosubstituted acetylenes with quaternary ammonium pendant groups
• Alkynylation and hydrogenation reactions
• Hetero-Diels-Alder/ring-opening reactions
• Insertion of carbenes into O-H bonds of alcohols
• Cyclopropanation of olefins
• Hydroformylation reactions

安全信息

• 象形图: GHS08,GHS07
• 警示用语：: Danger
• 危险声明: H302,H315,H317,H319,H334,H335,H373
• 预防措施声明: P260 - P264 - P280 - P301 + P312 - P302 + P352 - P305 + P351 + P338
• 危险分类: Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 3
• 靶器官: Central nervous system,Peripheral nervous system, Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves