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Merck

247219

Sigma-Aldrich

6-溴-1-己烯

95%

别名:

1-溴-5-己烯, 5-己烯-1-基溴, 5-己烯基溴, 6-溴己烯

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About This Item

线性分子式:
Br(CH2)4CH=CH2
CAS号:
分子量:
163.06
Beilstein:
506203
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
价格与库存信息目前不能提供

方案

95%

表单

liquid

杂质

<3% DMF

折射率

n20/D 1.465 (lit.)

沸点

47-51 °C/16 mmHg (lit.)

密度

1.22 g/mL at 25 °C (lit.)

官能团

alkyl halide
allyl
bromo

SMILES字符串

BrCCCCC=C

InChI

1S/C6H11Br/c1-2-3-4-5-6-7/h2H,1,3-6H2

InChI key

RIMXEJYJXDBLIE-UHFFFAOYSA-N

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一般描述

6-溴-1-己烯与镁反应生成格氏试剂 [1]。已用 X 射线光电子能谱和程序升温脱附研究了 6-溴-1-己烯在 Ni (100) 表面的热化学[2]

应用

6-溴-1-己烯用于制备环氧化物,6-溴-1,2-环氧己烷 [3]。它也被用于在液氨中通过对苯二甲腈的阴离子还原形式简单、直接地制备 4-烯基苯甲腈 [4]

警示用语:

Danger

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

129.2 °F - closed cup

闪点(°C)

54 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The formation of grignard compounds-III: The influence of the solvent.
Bodewitz HWHJ, et al.
Tetrahedron, 31(8), 1053-1063 (1975)
Cyclization of 6-bromo-1, 2-epoxyhexane promoted by metal-halogen exchange: unexpected regioselectivity.
Babler JH and Bauta WE.
Tetrahedron Letters, 25(39), 4323-4324 (1984)
Synlett, 1616-1616 (2007)
Thermal chemistry of 1, 6-diiodohexane on Ni (100) single-crystal surfaces: Mimicking cyclization reactions.
Tjandra S and Zaera F.
The Journal of Physical Chemistry A, 103(!4), 2312-2320 (1999)
Hiroshi Toda et al.
Applied and environmental microbiology, 81(6), 1919-1925 (2015-01-04)
We describe the development of biocatalysis for producing optically pure straight-chain (S)-epoxyalkanes using styrene monooxygenase of Rhodococcus sp. strain ST-10 (RhSMO). RhSMO was expressed in the organic solvent-tolerant microorganism Kocuria rhizophila DC2201, and the bioconversion reaction was performed in an

Questions

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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