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202509

Sigma-Aldrich

聚乙二醇甲基醚

average Mn 2,000, methoxy, hydroxyl

别名:

mPEG, 甲氧基聚乙二醇, 聚乙二醇单甲醚

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About This Item

线性分子式:
CH3(OCH2CH2)nOH
CAS号:
9004-74-4
MDL编号:
MFCD00084416
UNSPSC代码:
12162002
PubChem化学物质编号:
24852095
NACRES:
NA.23

产品名称

聚乙二醇甲基醚, average Mn ~2,000

蒸汽密度

>1 (vs air)

蒸汽压

0.05 mmHg ( 20 °C)

表单

flakes (or pellets)

分子量

average Mn ~2,000

粘度

54.6 cSt(210 °F)(lit.)

转变温度

Tm 52 °C

官能团

hydroxyl

SMILES字符串

O(CCO)C

InChI

1S/C3H8O2/c1-5-3-2-4/h4H,2-3H2,1H3

InChI key

XNWFRZJHXBZDAG-UHFFFAOYSA-N

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相关类别

一般描述

它是聚乙二醇（PEG）大分子单体，具有由甲基醚组成的反应性链端。PEG链末端的醚化可以通过在碱性条件下使其与烷基卤化物进行反应来实现。mPEG可以进行交联以形成水凝胶;聚合反应可以通过氧化还原反应或自由基引发剂进行引发。

应用

插入聚（乙二醇）甲基醚结合的树状聚合物可作为抗癌药物的载体。这种新型药物载体具有生物相容性表面和药物的内部封装。

它可作为一种成孔剂，以制备用于去除大分子的超滤膜。

还可将其作为起始材料，用于制备生物可降解的聚（L-丙氨酸）与mPEG的两亲性共聚物。

特点和优势

插入聚（乙二醇）甲基醚(mPEG)侧链可增强聚合物基质的亲水性和柔韧性。

储存分类代码

11 - Combustible Solids

WGK

WGK 1

闪点(°F)

359.6 °F - closed cup

闪点(°C)

182 °C - closed cup

个人防护装备

Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000197564
0000197564
0000338361
MKCV6083
MKCV9757

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聚（乙二醇） BioUltra, 2,000

Sigma-Aldrich

84797

聚（乙二醇）

Yi Wei et al.
Langmuir : the ACS journal of surfaces and colloids, 28(39), 13984-13992 (2012-09-04)
The microcosmic mechanisms of protein (recombinant human growth hormone, rhGH) incomplete release and stability from amphiphilic poly(monomethoxypolyethylene glycol-co-D,L-lactide) (mPEG-PLA, PELA) microspheres were investigated. PELA with different hydrophilicities (PELA-1, PELA-2, and PELA-3) based on various ratios of mPEG to PLA were
Junhwa Shin et al.
Molecular pharmaceutics, 9(11), 3266-3276 (2012-10-04)
A family of 3-methoxypoly(ethylene glycol)-vinyl ether-1,2-dioleylglycerol (mPEG-VE-DOG) lipopolymer conjugates, designed on the basis of DFT calculations to possess a wide range of proton affinities, was synthesized and tested for their hydrolysis kinetics in neutral and acidic buffers. Extruded ∼100 nm
Yunki Lee et al.
Colloids and surfaces. B, Biointerfaces, 102, 585-589 (2012-10-30)
The control of biological interactions that occur at material-cell/blood interfaces is of great importance to help maximize in vitro and in vivo performance of biomedical devices. PEGylation has been extensively used as an effective surface modification tool that can alter
Yiyi Yu et al.
Journal of pharmaceutical sciences, 102(3), 1054-1062 (2013-01-03)
To promote the application of methoxy poly(ethylene glycol)-cholesterol (mPEG-Chol), mPEG-Chol was used to prepare core-shell micelles encapsulating poorly water-soluble docetaxel (DTX-PM) by modified cosolvent evaporation method. Approaches to enhance DTX entrapment efficiency (EE) and minimize particle size were investigated in
Pengxiang Zhao et al.
Chemical communications (Cambridge, England), 49(31), 3218-3220 (2013-03-14)
"Click" chemistry now offers access to a great variety of triazoles, and the first example of a strategy to stabilize gold nanoparticles (AuNPs) with a new 1,2,3-triazole-mPEG ligand is developed here together with preliminary examples of possible applications.
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