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Merck

157902

Sigma-Aldrich

1,3-二溴-5,5-二甲基海因

98%

别名:

1,3-二溴-5,5-二甲基乙内酰脲

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About This Item

经验公式(希尔记法):
C5H6Br2N2O2
CAS号:
分子量:
285.92
Beilstein:
146024
EC號碼:
MDL號碼:
分類程式碼代碼:
12352101
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

98%

mp

197-199 °C (dec.) (lit.)

SMILES 字串

CC1(C)N(Br)C(=O)N(Br)C1=O

InChI

1S/C5H6Br2N2O2/c1-5(2)3(10)8(6)4(11)9(5)7/h1-2H3

InChI 密鑰

VRLDVERQJMEPIF-UHFFFAOYSA-N

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應用

用于烷氧基苯甲酸的芳香溴化以及烯烃的溴氟化。

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Ox. Sol. 3 - Skin Corr. 1B - Skin Sens. 1

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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M Hilp
Die Pharmazie, 59(8), 612-614 (2004-09-24)
Iodine values (iodine numbers) of several fixed oils and lard can be determined in ethyl acetate, an easily biodegredable solvent, instead of chloroform according to PH. EUR. 2002. Iodine monobromide has been replaced by 1,3-dibromo-5,5-dimethylhydantoin (DBH) and potassium iodide (KI)
M Hilp
Die Pharmazie, 57(6), 393-395 (2002-07-16)
Elemental bromine serves as oxidant for the identification of propylthiouracil, 2-thiouracil and sulphur according to PH. EUR. 2002. Phenol is identified according to PH. EUR. 2002 with bromine water as the sparingly water-soluble 2,4,4,6-tetrabromo-2,5-cyclohexadiene-1-one. These tests can be performed better
Soni Kamlesh Madhusudan et al.
Carbohydrate research, 340(3), 497-502 (2005-02-01)
Exchange of acyclic glycosyl dithioacetals to their O,O-acetals has been achieved by a generalized reaction protocol mediated by 1,3-dibromo-5,5-dimethylhydantoin under mild, metal-free and neutral conditions. This methodology has been extended to the synthesis of alkyl glycofuranosides.
M Hilp
Die Pharmazie, 56(7), 548-551 (2001-08-08)
The identification of lactate according to Ph. Eur. 1997 and DAB 2000 uses the oxidation of lactic acid to pyruvic acid by boiling with bromine water in sulphuric acid. Acetaldehyde arising by decarboxylation is detected according to Legal applying a
M Hilp
Die Pharmazie, 57(1), 45-48 (2002-02-12)
PH. EUR. 2002 uses elemental bromine performing iron limit tests for maleic acid (iron 5 ppm) and titanium dioxide (iron 200 ppm). 1,3-Dibromo-5,5-dimethylhydantoin (DBH) can replace bromine water. For the iron limit test of maleic acid bivalent iron is oxidized

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