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Merck

147117

Sigma-Aldrich

苄基三甲基溴化铵

97%

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About This Item

线性分子式:
C6H5CH2N(Br)(CH3)3
CAS号:
分子量:
230.14
Beilstein:
3917251
EC號碼:
MDL號碼:
分類程式碼代碼:
12352116
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

mp

230-232 °C (lit.)

SMILES 字串

[Br-].C[N+](C)(C)Cc1ccccc1

InChI

1S/C10H16N.BrH/c1-11(2,3)9-10-7-5-4-6-8-10;/h4-8H,9H2,1-3H3;1H/q+1;/p-1

InChI 密鑰

UUZYBYIOAZTMGC-UHFFFAOYSA-M

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應用

苄基三甲基溴化铵 (BTMAB) 可作为起始材料,与CrO3和HF水溶液反应合成苄基三甲基氟铬酸铵 (BTMAFC)。BTMAFC可作为高效氧化剂,将肟选择性氧化为酮或醛,以及将一级和二级醇、烯丙醇和苯甲醇氧化成它们相应的羰基化合物形式。

BTMAB还可用作:      
  • 氧化剂,在DMSO的存在下将单取代苄胺氧化成对应的醛亚胺。      
  • 在镍催化剂的作用下,作为苄基化试剂将芳基酰胺C-H键苯甲酰化。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Benzyltrimethylammonium fluorochromate (VI): a novel, efficient and selective oxidant
Kassaee MZ, et al.
Acta Chimica Slovenica, 51, 743-750 (2004)
Benzyltrimethylammonium fluorochromate (VI): a novel, efficient and selective oxidant
Rekha S and Seema K
Indian Journal of Chemistry, 41A, 541-546 (2002)
Herman Odens et al.
Chemical & pharmaceutical bulletin, 62(9), 933-936 (2014-09-02)
Fatty acid synthase (FASN) is the enzyme that synthesizes fatty acids de novo in human cells. Although FASN is generally expressed at low levels in most normal tissues, its expression is highly upregulated in many cancers. Consistent with this notion
L Sangeetha Vedula et al.
Archives of biochemistry and biophysics, 466(2), 260-266 (2007-08-07)
Trichodiene synthase is a terpenoid cyclase that catalyzes the cyclization of farnesyl diphosphate (FPP) to form the bicyclic sesquiterpene hydrocarbon trichodiene (89%), at least five sesquiterpene side products (11%), and inorganic pyrophosphate (PP(i)). Incubation of trichodiene synthase with 2-fluorofarnesyl diphosphate

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