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Merck

145947

Sigma-Aldrich

四氯环丙烯

98%

别名:

1,2,3,3-四氯环丙烯, 全氯环丙烯, 四氯环丙烯, 四氯环丙烯酮

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About This Item

经验公式(希尔记法):
C3Cl4
CAS号:
分子量:
177.84
Beilstein:
1099206
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.507 (lit.)

bp

125-130 °C (lit.)

密度

1.45 g/mL at 25 °C (lit.)

官能基

chloro

儲存溫度

2-8°C

SMILES 字串

ClC1=C(Cl)C1(Cl)Cl

InChI

1S/C3Cl4/c4-1-2(5)3(1,6)7

InChI 密鑰

BLZOHTXDDOAASQ-UHFFFAOYSA-N

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一般說明

四氯环丙烯经过电化学还原 丁基二甲基硅烷化反应生成 1,2,3- 丁基二甲基硅基)环丙烯 。它在二氯甲烷和 AlCl 3 中与二茂铁发生烷基化反应生成 2,3-二茂铁环丙烯酮

應用

采用四氯环丙烯,制备用于合成 3,3-二乙基和 3,3-二苄基-1,2-二茂铁基环丙烯的起始试剂

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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H A Buchholz et al.
Proceedings of the National Academy of Sciences of the United States of America, 96(18), 10003-10005 (1999-09-01)
Electrochemical reductive tert-butyldimethylsilylation of tetrachlorocyclopropene to 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene, a potential strained precursor for Diels-Alder and related cycloaddition reactions, is described. By hydride abstraction with nitrosonium tetrafluoroborate, 1,2,3-tris(tert-butyldimethylsilyl)cyclopropene is ionized quantitatively to Hückeloid 2pi aromatic tris(tert-butyldimethylsilyl)cyclopropenium tetrafluoroborate.
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Non-viral vectors for the transfection of genetic material are at the frontier of medical science. In this article, we introduce for the first time, cyclopropenium-containing nanoparticles as a cationic carrier for gene transfection, as an alternative to the common quaternary
Elena I Klimova et al.
Organic & biomolecular chemistry, 1(24), 4458-4464 (2004-01-20)
Reactions of 2,3-diferrocenylcyclopropenone 1 with ethyl- and benzylmagnesium chlorides afford 3,3-diethyl-and 3,3-dibenzyl- 1,2-diferrocenylcyclopropenes 2 and 3, respectively, and products of nucleophilic opening of the three-membered ring resulting from the addition of RMgCl to the carbonyl group, viz., saturated ketones(4,5-diferrocenylheptan-3-ones 4a,b
Jesús García-Valdés et al.
Journal of inorganic biochemistry, 197, 110689-110689 (2019-05-18)
Bis-cations with two 2,3-diferrocenylcyclopropenium fragments 3a-d, and the cis-2-(1,2-diferrocenylvinyl)-2-imidazolinium tetrafluoroborates 4a, d or the cis-2-(1,2-diferrocenylvinyl)-3,4,5,6-tetrahydropyrimidin-2-ium tetrafluoroborates 4b, c were obtained by interactions of 2,3-diferrocenyl-1-ethoxycyclopropenium tetrafluoroborate 1 with bis-1,4-N,N-(2a, d) or bis-1,5-N,N-(2b, c) nucleophiles. The reactions of 3a-d with sodium azide

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