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Merck

135895

Sigma-Aldrich

二甲氨基硫代甲酰氯

97%

别名:

1-Chloro-N,N-dimethylthioformamide

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About This Item

线性分子式:
(CH3)2NCSCl
CAS号:
分子量:
123.60
Beilstein:
635823
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

97%

形狀

solid

bp

90-95 °C/0.5 mmHg (lit.)

mp

39-43 °C (lit.)

溶解度

chloroform: soluble 100 mg/mL, clear to very slightly hazy, very faintly yellow

儲存溫度

2-8°C

SMILES 字串

CN(C)C(Cl)=S

InChI

1S/C3H6ClNS/c1-5(2)3(4)6/h1-2H3

InChI 密鑰

PHWISQNXPLXQRU-UHFFFAOYSA-N

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應用

二甲氨基硫代甲酰氯被用于吡啶-N-氧化物的化学选择性脱氧反应。 它被用于合成 (±)-硫代胡桐素A。它被用作二甲氨基硫代甲酸酯合成中的起始试剂

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

208.4 °F - closed cup

閃點(°C)

98 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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A synthesis of (?)-thia-calanolide A, its resolution and in vitro biological evaluation.
Chopade AU, et al. et al.
Arabian Journal of Chemistry (2012)
Journal of Heterocyclic Chemistry, 44, 487-487 (2007)
D K Barma et al.
Organic letters, 5(25), 4755-4757 (2003-12-05)
Dimethylthiocarbamates (DMTCs), prepared from the corresponding alcohols using commercial dimethylthiocarbamoyl chloride, are spectrally simple, achiral, and nonpolar. DMTCs are moderately to highly stable to a wide range of reagents and conditions including metal hydrides, hydroboration, ylides, NaOH, HCl, organolithiums, Grignards
Harley D Betts et al.
Molecules (Basel, Switzerland), 25(19) (2020-10-07)
Silver(I)-based coordination polymers or metal-organic frameworks (MOFs) display useful antibacterial properties, whereby distinct materials with different bonding can afford control over the release of silver(I) ions. Such silver(I) materials are comprised of discrete secondary building units (SBUs), and typically formed

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