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一般描述
当存在催化配体和二甲基锌时，在0℃下，2-氯苯甲醛与苯乙炔发生炔基化反应，形成联萘衍生的氨基醇。
应用
2-氯苯甲醛已被用于通过β-酮酯、醛和硫脲的一锅法三组分Biginelli环合反应生成各种官能化二氢嘧啶衍生物的小型专一化合物库。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 2
闪点(°F)
206.6 °F - closed cup
闪点(°C)
97 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
Enantioselective alkynylation of aromatic aldehydes catalyzed by new chiral amino alcohol-based ligands.
Lu G, et al.
Tetrahedron Asymmetry, 12(15), 2147-2152 (2001)
M Rogojerov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(7), 1661-1670 (2005-04-12)
Vibrational analysis of the two conformers of furfural and 2-chlorobenzaldehyde has been carried out on the basis of their IR and Raman spectra measured in isotropic and anisotropic (nematic liquid crystalline) solvent. The average orientation of the individual conformers in
Percutaneous absorption of 14C-labelled 2-chlorobenzaldehyde in rats. Metabolism and toxicokinetics.
E C Rietveld et al.
European journal of drug metabolism and pharmacokinetics, 13(4), 231-240 (1988-10-01)
2-Chlorobenzaldehyde might be produced when a moist skin is exposed to the riot control agent CS. CS-hydrolysis to 2-chlorobenzaldehyde and malononitrile occurs both in vitro and in vivo. No quantitative data have thus far been reported with respect to the
M Anzaldi et al.
European journal of medicinal chemistry, 35(9), 797-803 (2000-09-28)
Vilsmeier reagents react with alpha/beta-ionones and carvone to produce aldehydes 7-11 in a one-step procedure. The indene derivative 11, which came from the double iminoalkylation of carvone and ring closure with the elimination of dimethylamine, was practically odourless, while all
E Schmid et al.
Mutagenesis, 6(4), 303-305 (1991-07-01)
The aneuploidy inducing capacity of 2-chlorobenzylidene malonitrile (CS), a chemical used as a riot control agent, and its hydrolysis products o-chlorobenzaldehyde and malonitrile was studied at various exposure conditions in V79 Chinese hamster cells. Chromosomes were counted in metaphase preparations
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