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质量水平
方案
98%
折射率
n20/D 1.523 (lit.)
沸点
39-40 °C/1 mmHg (lit.)
溶解性
THF: soluble
密度
1.18 g/mL at 25 °C (lit.)
官能团
thioester
SMILES字符串
O=C1CCCS1
InChI
1S/C4H6OS/c5-4-2-1-3-6-4/h1-3H2
InChI key
KMSNYNIWEORQDJ-UHFFFAOYSA-N
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一般描述
γ-硫代丁酸内酯与缩水甘油基苯基醚共聚形成聚酯硫醚 。
应用
γ-硫代丁酸内酯被用于终止 ω 开环聚合-十五内酯合成双功能聚酯 。γ-硫代丁酸内酯还被用于研究木质素降解担子菌 云芝 对含硫杂环化合物的代谢机理。
其他客户在看
Tiny droplets make a big splash.
Michael Eisenstein
Nature methods, 3(2), 71-71 (2006-02-14)
Nishikubo et al.
Macromolecules, 31(15), 4746-4752 (1998-07-29)
Poly(ester-alt-sulfide) (polymer 1) was synthesized by the alternating copolymerization of glycidyl phenyl ether (GPE) with gamma-thiobutyrolactone (TBL) catalyzed by either quaternary onium salts or crown ether complexes. The copolymerization proceeded to produce polymer 1 with good yields in neat or
One-pot difunctionalization of poly (ω-pentadecalactone) with thiol-thiol or thiol-acrylate groups, catalyzed by Candida antarctica lipase B.
Takwa M, et al.
Macromolecular Rapid Communications, 27(22), 1932-1936 (2006)
K D Holland et al.
Brain research, 615(1), 170-174 (1993-06-25)
Effects of alkyl-substituted gamma-butyrolactones and gamma-thiobutyrolactones on [35S]t-butylbicyclophosphorothionate (35S-TBPS) dissociation from the picrotoxinin receptor were studied. Unlike picrotoxinin, these lactones accelerated the dissociation rate of 35S-TBPS. Thus, previous reports that these lactones change the Kd but not the Bmax of
Jonathan Garel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(15), 4144-4152 (2006-02-03)
Homocysteine thiolactone (tHcy) is deemed a risk factor for cardiovascular diseases and strokes, presumably because it acylates the side chain of protein lysine residues ("N-homocysteinylation"), thereby causing protein damage and autoimmune responses. We analysed the kinetics of hydrolysis and aminolysis
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