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433497

Sigma-Aldrich

Poly(propylene glycol), tolylene 2,4-diisocyanate terminated

average Mn ~2,300 (narrow MW distribution), isocyanate ~3.6 wt. %

Synonym(s):

Polypropylene glycol-toluene diisocyanate copolymer, Tolylene diisocyanate-polypropylene glycol polymer

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

form

viscous liquid

Quality Level

mol wt

average Mn ~2,300 (narrow MW distribution)
degree of polymerization ~34

composition

isocyanate, ~3.6 wt. %

hardness

80 (Shore A, reacted with MOCA)

impurities

<0.1% residual TDI

refractive index

n20/D 1.4742

viscosity

≤1,700 cP(40 °C)(lit.)

density

1.05 g/mL at 25 °C

SMILES string

CC(O)CO.Cc1ccc(cc1N=C=O)N=C=O

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Application

Idler rollers and adhesive-handling pads.

Features and Benefits

Lower viscosity than conventional polyurethane oligomers. Aromatic isocyanate is more reactive than aliphatic isocyanate. Aromatic isocyanates are less light stable than aliphatic isocyanates.

Physical form

Polyurethane prepolymer.

Pictograms

Health hazardExclamation mark

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup


Certificates of Analysis (COA)

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[Use of KL-3 medical glue in surgery of the organs of the hepatopancreatoduodenal area].
V S Zemskov et al.
Khirurgiia, (8)(8), 37-39 (1985-08-01)
[The use of the polyurethane adhesive compound KL-3 for treating varicosities of the surface veins].
Iu M Polous et al.
Klinichna khirurhiia, (7)(7), 26-27 (1996-01-01)
I V Titarenko et al.
Vestnik khirurgii imeni I. I. Grekova, 152(3-4), 17-23 (1994-03-01)
Results of experimental investigations of using polymer compositions KL-3, including modifications with ionol ("Adgenol") and levamisol in 18 rabbits with injuries of the liver are presented. It has been established that 3 and 6 months after using the mentioned compositions
[Use of medical glues MK-6 and KL-3 in surgical endocrinology].
I V Komissarenko et al.
Klinicheskaia khirurgiia, (12)(12), 19-20 (1985-01-01)
[Plombage of pathological pleural cavities].
V Ia Dzhugostran
Grudnaia khirurgiia (Moscow, Russia), (5)(5), 58-60 (1987-09-01)

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