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491748

Sigma-Aldrich

4-(Bromomethyl)pyridine hydrobromide

97%

Synonym(s):

(4-Pyridyl)methyl bromide hydrobromide, 4-(Bromomethyl)pyridine monohydrobromide, 4-Picolyl bromide hydrobromide

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About This Item

Empirical Formula (Hill Notation):
C6H6BrN · HBr
CAS Number:
73870-24-3
Molecular Weight:
252.93
MDL number:
MFCD01863545
UNSPSC Code:
12352100
PubChem Substance ID:
24872681
NACRES:
NA.22

Quality Level

100

Assay

97%

mp

189-192 °C (lit.)

SMILES string

Br[H].BrCc1ccncc1

InChI

1S/C6H6BrN.BrH/c7-5-6-1-3-8-4-2-6;/h1-4H,5H2;1H

InChI key

VAJUUDUWDNCECT-UHFFFAOYSA-N

Related Categories

General description

4-(Bromomethyl)pyridine hydrobromide is a substituted pyridine. It reacts with 1,2-ethanediamine and 1,3-propanediamine to form the corresponding diamines.

Application

4-(Bromomethyl)pyridine hydrobromide may be used in the preparation of:
  • 3-(4-pyridylmethyl)-2′,3′-di-O-oleyl-5′-O-(4,4′-dimethoxytriphenylmethyl)uridine
  • 3-(4-pyridylmethyl)-3′-O-oleyl-5′-O-(4,4-dimethoxytriphenylmethyl)-thymidine
  • 1,4-bis(N-hexyl-4-pyridinium)butadiene diperchlorate
It may also be used in the preparation of the following benzoxazine derivatives:
  • 2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • 8-methyl-2-morpholin-4-yl-7-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one
  • 2-morpholin-4-yl-8-(pyridin-4-ylmethoxy)-4H-1,3-benzoxazin-4-one

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Photoinduced electron transfer in supramolecular complexes of a p-extended viologen with porphyrin monomer and dimer.
Fukuzumi S, et al.
Royal Society of Chemistry Advances, 2(9), 3741-3747 (2012)
Cristiane F da Costa et al.
Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie, 63(1), 40-42 (2008-02-12)
We report in this work the preparation and the in vitro antileishmanial activity of a series of long chains N-monoalkylated diamines and two pyridinediamine derivatives. Several compounds, tested for their in vitro antiproliferative activity against Leishmania amazonensis and Leishmania chagasi
Luca Simeone et al.
Molecular bioSystems, 7(11), 3075-3086 (2011-09-08)
Novel thymidine- or uridine-based nucleolipids, containing one hydrophilic oligo(ethylene glycol) chain and one or two oleic acid residues (called ToThy, HoThy and DoHu), have been synthesized with the aim to develop bio-compatible nanocarriers for drug delivery and/or produce pro-drugs. Microstructural
Saleh Ihmaid et al.
European journal of medicinal chemistry, 45(11), 4934-4946 (2010-08-31)
A number of new 2-amino-[5, 6, 7 and 8]-O-substituted 1,3-benzoxazines, and 2-amino 8-methyl-7-O-substituted-1,3-benzoxazines were synthesized. Thirty one new compounds were tested for their effect on collagen induced platelet aggregation and it was found that the most active compounds were 8-methyl-2-morpholin-4-yl-7-(pyridin-3-ylmethoxy)-4H-1,3-benzoxazin-4-one

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