38270

Diisopropyl ether

puriss. p.a., ≥98.5% (GC)

• Synonyme(s) : Isopropyl ether
• Formule linéaire : (CH₃)₂CHOCH(CH₃)₂
• Numéro CAS: 108-20-3
• Poids moléculaire : 102.17
• Numéro Beilstein : 1731256
• Numéro CE : 203-560-6
• Numéro MDL: MFCD00008880
• Code UNSPSC : 12191502
• ID de substance PubChem : 329755758
• Nomenclature NACRES : NA.07

Propriétés

• Densité de vapeur: 3.5 (vs air)
• Niveau de qualité: 200
• Pression de vapeur: 120 mmHg ( 20 °C)
• Qualité: puriss. p.a.
• Pureté: ≥98.5% (GC)
• Forme: liquid
• Température d'inflammation spontanée: 827 °F
• Contient: ~0.001% 2,6-di-tert-butyl-4-methylphenol as stabilizer
• Limite d'explosivité: 1-21 %, 100 °F
• Impuretés: ≤0.001% peroxides (as H₂O₂); ≤0.005% free acid (as C₂H₅COOH); ≤0.1% water; ≤0.5% isopropanol (GC)
• Résidus d'évap.: ≤0.002%
• Indice de réfraction: n20/D 1.367 (lit.); n20/D 1.368
• Point d'ébullition: 68-69 °C (lit.)
• Pf: −85 °C (lit.)
• Densité: 0.724 g/mL at 20 °C; 0.725 g/mL at 25 °C (lit.)
• Traces de cations: Al: ≤0.5 mg/kg; Ba: ≤0.1 mg/kg; Bi: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.1 mg/kg; K: ≤0.5 mg/kg; Li: ≤0.1 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Mo: ≤0.1 mg/kg; Na: ≤0.5 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.1 mg/kg; Sr: ≤0.1 mg/kg; Zn: ≤0.1 mg/kg
• Chaîne SMILES: CC(C)OC(C)C
• InChI: 1S/C6H14O/c1-5(2)7-6(3)4/h5-6H,1-4H3
• Clé InChI: ZAFNJMIOTHYJRJ-UHFFFAOYSA-N

Description

Description générale

Diisopropyl ether is a colorless liquid. It is widely used as a solvent for the isolation of fats and oils. It can be synthesized from isopropyl alcohol. Its mixture with isooctane has been added to the gasoline fuel as an antiknocking agent. Its synthesis from propylene and water in a single-pass trickle-bed reactor in the presence of an ion-exchange resin catalyst Amberlyst 15 has been proposed.

Application

Diisopropyl ether may be employed as a solvent for the preparation of aliphatic and aromatic cyanohydrins.

Informations sur la sécurité

• Pictogrammes: GHS02,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H336
• Conseils de prudence: P210 - P233 - P240 - P241 - P242 - P243
• Classification des risques: Flam. Liq. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Risques supp: EUH019,EUH066
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): -20.2 °F - closed cup
• Point d'éclair (°C): -29 °C - closed cup