394874

1-(Trimethylsilyl)imidazole

for GC derivatization, LiChropur^™

• Synonyme(s) : N-Triméthylsilylimidazole
• Formule empirique (notation de Hill): C₆H₁₂N₂Si
• Numéro CAS: 18156-74-6
• Poids moléculaire : 140.26
• Numéro Beilstein : 606148
• Numéro CE : 242-040-3
• Numéro MDL: MFCD00005280
• Code UNSPSC : 12000000
• ID de substance PubChem : 329755874
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: for GC derivatization; LiChropur^™
• Niveau de qualité: 100
• Pureté: ≥94.0%
• Pertinence de la réaction: reagent type: derivatization reagent; reaction type: Silylations
• Technique(s): gas chromatography (GC): suitable
• Indice de réfraction: n20/D 1.475 (lit.)
• Point d'ébullition: 93-94 °C/14 mmHg (lit.)
• Densité: 0.956 g/mL at 25 °C (lit.)
• Chaîne SMILES: C[Si](C)(C)n1ccnc1
• InChI: 1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
• Clé InChI: YKFRUJSEPGHZFJ-UHFFFAOYSA-N

Description

Description générale

1-(Trimethylsilyl)imidazole (TMSIM) has high silyl donor ability. It does not react with amino groups and also does not help in formation of enol-ether on unprotected ketone groups. It is useful as a silylating agent for ecdysones, norepinephrine, dopamine, steroids, sugars, sugar phosphates and ketose isomers.

Powerful silylating agent, particularly for alcohols; Synthesis of acyl imidazolides

Application

1-(Trimethylsilyl) imidazole may be used for the synthesis an O-silylated derivative of a hexahomotriazacalix[3]arene. It may also be used for the silylation of Ti-MCM-41 catalyst, to study its effect on the olefin epoxidation with aqueous H₂O₂, 1-(Trimethylsilyl) imidazole was found to improve the hydrophobicity and the catalytic performance of Ti-MCM-41.

Learn more in the Product Information

Autres remarques

Reagent for trimethylsilyl and trimethylsilyl ether.

Informations légales

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS02,GHS07
• Mention d'avertissement: Danger
• Mentions de danger: H225,H302,H315,H319
• Conseils de prudence: P210 - P233 - P240 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
• Code de la classe de stockage: 3 - Flammable liquids
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 42.8 °F - closed cup
• Point d'éclair (°C): 6 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter