B1334

Benzaldehyde

ReagentPlus^®, ≥99%

• Synonyme(s) : Huile essentielle artificielle d’amandes
• Formule linéaire : C₆H₅CHO
• Numéro CAS: 100-52-7
• Poids moléculaire : 106.12
• Numéro Beilstein : 471223
• Numéro CE : 202-860-4
• Numéro MDL: MFCD00003299
• Code UNSPSC : 12352100
• eCl@ss : 39023701
• ID de substance PubChem : 57653918
• Nomenclature NACRES : NA.21

Propriétés

• Densité de vapeur: 3.7 (vs air)
• Niveau de qualité: 200
• Pression de vapeur: 4 mmHg ( 45 °C)
• Gamme de produits: ReagentPlus^®
• Pureté: ≥99%
• Forme: liquid
• Température d'inflammation spontanée: 374 °F
• Limite d'explosivité: 1.4 %, 20 °F
• Indice de réfraction: n20/D 1.545 (lit.)
• pH: 5.9 (20 °C)
• Point d'ébullition: 178-179 °C (lit.)
• Pf: −26 °C (lit.)
• Densité: 1.044 g/cm³ at 20 °C (lit.)
• Groupe fonctionnel: aldehyde; phenyl
• Chaîne SMILES: O=Cc1ccccc1
• InChI: 1S/C7H6O/c8-6-7-4-2-1-3-5-7/h1-6H
• Clé InChI: HUMNYLRZRPPJDN-UHFFFAOYSA-N

Description

Description générale

Benzaldehyde is an aromatic aldehyde. Rotational transitions in benzaldehyde have been explained based on its microwave absorption spectrum. The conversion of benzaldehyde into reduced compounds in the presence of metal oxides has been studied. SmFeO₃ (perovskite-type oxide catalyst) catalyzed cyanosilylation reaction of benzaldehyde with trimethylsilyl cyanide (TMSCN) has been reported.

Application

Benzaldehyde has been used as a standard in the quantification of Achillea ligustica essential oil by GC-MS (Gas Chromatography-Mass Spectrometry).

Benzaldehyde may be used in the following studies:

• Preparation of optically active 1-phenylpropan-1-ol.
• Synthesis of meso-tetraphenylporphins and chlorins.
• As a test compound to study oxidative amidation reaction of aliphatic primary/secondary amines using N-heterocyclic carbine as a catalyst.
• Synthesis of 2-phenyl-2,3-dihydro-4H-pyran-4-one with high enantioselectivity by hetero-Diels-Alder (HDA) reaction with Danishefsky′s diene.

Qualité

Chlorine-free

Informations légales

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Informations sur la sécurité

• Pictogrammes: GHS08,GHS07,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H302 + H332,H315,H319,H335,H360Df,H411
• Conseils de prudence: P273 - P301 + P312 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Classification des risques: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT SE 3
• Organes cibles: Respiratory system
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): 145.4 °F - closed cup
• Point d'éclair (°C): 63 °C - closed cup
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter