39405

4-(Dimethylamino)pyridine

purum, ≥98.0% (NT)

• Synonyme(s) : N,N-Dimethylpyridin-4-amine, DMAP
• Formule empirique (notation de Hill): C₇H₁₀N₂
• Numéro CAS: 1122-58-3
• Poids moléculaire : 122.17
• Numéro Beilstein : 110354
• Numéro CE : 214-353-5
• Numéro MDL: MFCD00006418
• Code UNSPSC : 12352005
• ID de substance PubChem : 329755867
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: purum
• Niveau de qualité: 200
• Pureté: ≥98.0% (NT)
• Forme: crystals; pellets
• Pf: 108-110 °C (lit.); 111-114 °C
• Solubilité: methanol: 0.1 g/mL, clear, colorless to almost colorless
• Groupe fonctionnel: amine
• Chaîne SMILES: CN(C)c1ccncc1
• InChI: 1S/C7H10N2/c1-9(2)7-3-5-8-6-4-7/h3-6H,1-2H3
• Clé InChI: VHYFNPMBLIVWCW-UHFFFAOYSA-N

Description

Description générale

4-(Dimethylamino)pyridine is generally employed as a catalyst in the acylation of amines, alcohols, enolates, and phenols. It can also be used in the esterification of carboxylic acids. It is known to exhibit good catalytic activity in non-polar solvents.

Application

4-(Dimethylamino)pyridine can be used:

• As a capping agent in the preparation of water-soluble gold nanoparticles.
• As an initiator in the polymerization of epoxy monomers.
• As an auxiliary reagent in the electroless preparation of gold nanotubes applicable in catalysis.
• As a catalyst in the preparation of γ- and δ-lactones via iodolactonization of γ,δ-unsaturated carboxylic acids.

A highly efficient catalyst for acylation reactions

Autres remarques

Hypernucleophilic acylation catalyst. Review

Informations sur la sécurité

• Pictogrammes: GHS06,GHS08,GHS05,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H301 + H331,H310,H315,H318,H370,H411
• Conseils de prudence: P262 - P273 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338
• Classification des risques: Acute Tox. 2 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 1
• Organes cibles: Nervous system
• Code de la classe de stockage: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): 255.2 °F
• Point d'éclair (°C): 124 °C
• Équipement de protection individuelle: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges