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32972

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Lactofen

PESTANAL®, analytical standard

Synonyme(s) :

Ethyl O-[5-(2-chloro-α,α,α-trifluoro-p-tolyloxy)-2-nitrobenzoyl]-DL-lactate

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About This Item

Formule empirique (notation de Hill):
C19H15ClF3NO7
Numéro CAS:
Poids moléculaire :
461.77
Numéro MDL:
Code UNSPSC :
41116107
ID de substance PubChem :
Nomenclature NACRES :
NA.24

Qualité

analytical standard

Niveau de qualité

Gamme de produits

PESTANAL®

Durée de conservation

limited shelf life, expiry date on the label

Technique(s)

HPLC: suitable
gas chromatography (GC): suitable

Application(s)

agriculture
environmental

Format

neat

Chaîne SMILES 

CCOC(=O)C(C)OC(=O)c1cc(Oc2ccc(cc2Cl)C(F)(F)F)ccc1[N+]([O-])=O

InChI

1S/C19H15ClF3NO7/c1-3-29-17(25)10(2)30-18(26)13-9-12(5-6-15(13)24(27)28)31-16-7-4-11(8-14(16)20)19(21,22)23/h4-10H,3H2,1-2H3

Clé InChI

CONWAEURSVPLRM-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Lactofen is a broad-spectrum post-emergent herbicide. It acts by inhibiting protoporphyrinogen oxidase by causing lipid peroxidation of the cell membrane.

Application

Lactofen may be used as an analytical reference standard for the determination of the analyte in:
  • Environmental samples by high performance liquid chromatography (HPLC) coupled to tandem mass spectrometric detector (MS/MS), ultraviolet (UV) detector and circular dichroism (CD) detector.
  • Fruit and wheat flour matrices by on-line turbulent flow chromatography (TFC) combined with LC-MS/MS.
  • Agricultural products using gas chromatography coupled to flame photometric detector (GC-FPD).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Produits recommandés

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Informations légales

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogrammes

Exclamation markEnvironment

Mention d'avertissement

Warning

Mentions de danger

Classification des risques

Acute Tox. 4 Dermal - Aquatic Chronic 2

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves


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Certificats d'analyse (COA)

Lot/Batch Number

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Consulter la Bibliothèque de documents

Madge Y Graham
Plant physiology, 139(4), 1784-1794 (2005-11-22)
Lactofen belongs to the diphenylether class of herbicides, which targets protoporphyrinogen oxidase, which in turn causes singlet oxygen generation. In tolerant plants like soybean (Glycine max), the chemical nonetheless causes necrotic patches called "bronzing" in contact areas. Here it is
Jing Zhang et al.
Journal of hazardous materials, 341, 336-345 (2017-08-13)
A bacterial strain Za capable of degrading diphenyl ether herbicide lactofen was isolated and identified as Bacillus sp. This strain could degrade 94.8% of 50mgL
Coupled turbulent flow chromatography: LC-MS/MS method for the analysis of pesticide residues in grapes, baby food and wheat flour matrices.
Hollosi L, et al.
Chromatographia, 75(23-24), 1377-1393 (2012)
Irani Mukherjee et al.
Bulletin of environmental contamination and toxicology, 79(1), 49-52 (2007-06-30)
Lactofen, a member of the diphenyl ether chemical family, shows great potential for the control of broadleaf weeds associated with leguminous crops. It presents a high degree of selectivity when applied post-emergence to soybean and peanut crops. This paper presents
Serena Landini et al.
Phytochemistry, 62(6), 865-874 (2003-02-19)
Lactofen, the active ingredient of the soybean disease resistance-inducing herbicide, Cobra, induces large accumulations of isoflavone conjugates and aglycones in soybean tissues. The predominant isoflavones induced in cotyledon tissues are daidzein (and its conjugates) and formononetin and glycitein aglycones. The

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