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246816

Sigma-Aldrich

1,6-Hexanediol diacrylate

technical grade, 80%

Synonyme(s) :

Hexamethylene glycol diacrylate, Hexane-1,6-diyl diacrylate, HDODA

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About This Item

Formule linéaire :
[H2C=CHCO2(CH2)3-]2
Numéro CAS:
13048-33-4
Poids moléculaire :
226.27
Numéro CE :
235-921-9
Numéro MDL:
MFCD00008631
Code UNSPSC :
12162002
ID de substance PubChem :
24854827
Nomenclature NACRES :
NA.23

Qualité

technical grade

Niveau de qualité

200

Densité de vapeur

>1 (vs air)

Pression de vapeur

<0.01 mmHg ( 20 °C)

Pureté

80%

Forme

liquid

Contient

100 ppm monomethyl ether hydroquinone as inhibitor

Indice de réfraction

n20/D 1.456 (lit.)

Densité

1.01 g/mL at 25 °C (lit.)

Chaîne SMILES 

C=CC(=O)OCCCCCCOC(=O)C=C

InChI

1S/C12H18O4/c1-3-11(13)15-9-7-5-6-8-10-16-12(14)4-2/h3-4H,1-2,5-10H2

Clé InChI

FIHBHSQYSYVZQE-UHFFFAOYSA-N

Catégories apparentées

Description générale

1,6-Hexanediol diacrylate is a di-functional monomer commonly used in the polymer industry for producing various types of polymers. It is a viscous liquid, that is often used as a crosslinking agent in radical polymerization reactions. Additionally, it also finds use in various fields such as coatings, adhesives, 3D printing, medical devices, and textiles due to its excellent polymerization properties and versatility.

Application

1,6-Hexanediol diacrylate can be used as:
  • A monomer for the synthesis of poly(1,6-hexanediol diacrylate) (PHDA)-based polymer microspheres and bifunctional microcapsules. The resulting PHDA-based polymer embedded with TiO2 nanoparticles finds uses in various potential applications in fields such as sensing, drug delivery, and photonics.
  • A sensitizer in the UV-curable inks commonly used in the printing industry.
  • A cross-linking agent in conjunction with a photocatalytic system to modify cellulose material. The resulting crosslinked cellulose material finds uses in various potential applications such as paper manufacturing, textiles, and biomedical devices.
  • A monomer in the synthesis of polyurethane acrylate (PUA) which is used to produce polymer electrolytes for use in lithium batteries.
1,6-Hexanedioldiacrylate can be used as a starting material to synthesize:
  • A resin (copolymer of 1,6-hexanediol diacrylate and styrene) by suspension polymerization, which is applicable in the preparation of hydrophobic peptide sequences.
  • Monodispersed poly(HDDA)/TiO2 microspheres, applicable in the degradation of methylene blue.

Pictogrammes

Exclamation markEnvironment
GHS07,GHS09

Mention d'avertissement

Warning

Mentions de danger

H315,H317,H319,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Code de la classe de stockage

10 - Combustible liquids

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

235.4 °F - closed cup

Point d'éclair (°C)

113 °C - closed cup

Équipement de protection individuelle

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificats d'analyse (COA)

Lot/Batch Number
0000303855
MKCW7019
0000303855
MKCV4119
MKCQ7364

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Consulter la Bibliothèque de documents

J R Nethercott et al.
British journal of industrial medicine, 40(3), 241-250 (1983-08-01)
Seven workers exposed to ultraviolet printing inks developed contact dermatitis. Six cases were allergic and one irritant. A urethane acrylate resin accounted for five cases of sensitisation, one of which was also sensitive to pentaerythritol triacrylate and another also to
James L Horan et al.
ChemSusChem, 2(3), 226-229 (2009-01-27)
Highly conducive to high conductivity: Polyoxometalates were incorporated in the backbone of a hydrocarbon polymer to produce proton-conducting films. These first-generation materials contain large, dispersed clusters of polyoxometalates. Although the morphology of these films is not yet optimal, they already
Julia Kloeckner et al.
Bioconjugate chemistry, 17(5), 1339-1345 (2006-09-21)
Two biodegradable polycations based on hexanediol diacrylate linked oligoethylenimine (OEI) were synthesized by applying different reaction temperatures, 20 degrees C (LT-OEI-HD) and 60 degrees C (HT-OEI-HD). Their structural properties were analyzed by NMR, FTIR, and SEC/MALLS (size exclusion chromatography coupled
Terry W J Steele et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 80(1), 14-24 (2011-09-20)
Hexanediol diacrylate cross-linked oligoethylenimine (OEI-HD) is a non-viral polymeric vector designed to deliver siRNA. To achieve safe and effective in vivo siRNA delivery using this vector, the polyplex must have sufficient colloidal stability if administered intravenously or nebulized for delivery
Ebrahim Behroodi et al.
Scientific reports, 9(1), 19692-19692 (2019-12-25)
Projection microstereolithography (PµSL) is a promising additive manufacturing technique due to its low cost, accuracy, speed, and also the diversity of the materials that it can use. Recently it has shown great potentials in various applications such as microfluidics, tissue
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