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  • Synthesis of thioesters from carboxylic acids via acyloxyphosphonium intermediates with benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.

Synthesis of thioesters from carboxylic acids via acyloxyphosphonium intermediates with benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.

The Journal of organic chemistry (2009-07-22)
Purushothaman Gopinath, Ravindran Sasitha Vidyarini, Srinivasan Chandrasekaran
ZUSAMMENFASSUNG

An efficient protocol is reported for the synthesis of thioesters from carboxylic acids with use of acyloxy phosphonium salts as intermediates and benzyltriethylammonium tetrathiomolybdate as the sulfur transfer reagent.

MATERIALIEN
Produktnummer
Marke
Produktbeschreibung

Sigma-Aldrich
Benzyltrimethylammoniumchlorid, 97%
Sigma-Aldrich
Benzyltrimethylammoniumhydroxid -Lösung, 40 wt. % in H2O
Sigma-Aldrich
Benzyltrimethylammoniumhydroxid -Lösung, 40 wt. % in methanol
Sigma-Aldrich
Benzyltrimethylammoniumbromid, 97%
Sigma-Aldrich
Benzyltrimethylammoniumchlorid -Lösung, technical, ~60% in H2O