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Merck

650528

Sigma-Aldrich

Ethylacetat

HPLC Plus, for HPLC, GC, and residue analysis, 99.9%

Synonym(e):

EtOAc

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About This Item

Lineare Formel:
CH3COOC2H5
CAS-Nummer:
Molekulargewicht:
88.11
Beilstein:
506104
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12190000
PubChem Substanz-ID:
NACRES:
NA.21

Qualität

HPLC Plus
for residue analysis

Qualitätsniveau

Agentur

suitable for EPA ACB B21-02
suitable for EPA ACB B23-05b

Dampfdichte

3 (20 °C, vs air)

Dampfdruck

73 mmHg ( 20 °C)

Assay

99.9%

Form

liquid

Selbstzündungstemp.

801 °F

Expl.-Gr.

2.2-11.5 %, 38 °F

Methode(n)

HPLC: suitable
gas chromatography (GC): suitable

Verunreinigungen

≤0.03% water
≤1.0 ppb Fluorescence (quinine) at 365 nm
≤10 ng/L Pesticide residue analysis (as heptachlor epoxide)

Abdampfrückstand

≤0.0001%

Brechungsindex

n20/D 1.3720 (lit.)

bp

76.5-77.5 °C (lit.)

mp (Schmelzpunkt)

−84 °C (lit.)

Löslichkeit

alcohol: soluble(lit.)
chloroform: soluble(lit.)

Dichte

0.902 g/mL at 25 °C (lit.)

λ

H2O reference

UV-Absorption

λ: 256 nm Amax: ≤1.00
λ: 275 nm Amax: ≤0.05
λ: 300 nm Amax: ≤0.03
λ: 325-400 nm Amax: ≤0.005

Format

neat

SMILES String

CCOC(C)=O

InChI

1S/C4H8O2/c1-3-6-4(2)5/h3H2,1-2H3

InChIKey

XEKOWRVHYACXOJ-UHFFFAOYSA-N

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Allgemeine Beschreibung

Ethyl acetate (EA), a carboxylate ester, is bio-friendly organic solvent with a wide range of industrial applications. Its synthesis by reactive distillation and by acceptorless dehydrogenative dimerization of ethanol has been explored. Its ability as an acyl acceptor in the immobilized lipase-mediated preparation of biodiesel from crude vegetable oils has been examined. The complete degradation of ethyl acetate to CO2 using manganese octahedral molecular sieve (OMS-2) has been investigated. EA is an effective alternate solvent of diethyl ether, employed for the concentration of eggs, larvae, and cysts in fecal specimens during the Formalin-ether sedimentation technique. Acetaldehyde is reaction intermediate formed during the oxidative combustion of ethanol and ethyl acetate in the presence of copper oxide embedded on Ce-doped titania surface.

Anwendung

Für die HPLC, Spektrophotometrie, Umweltanalytik

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Piktogramme

FlameExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

Zielorgane

Central nervous system

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

24.8 °F - closed cup

Flammpunkt (°C)

-4 °C - closed cup


Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

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Dynamics and control of an ethyl acetate reactive distillation column.
Vora N and Daoutidis P.
Industrial & Engineering Chemistry Research, 40(3), 833-849 (2001)
Anatase thin films on glass from the chemical vapor deposition of titanium (IV) chloride and ethyl acetate.
O'Neill SA, et al.
Chemistry of Materials, 15(1), 46-50 (2003)
Christer Jansson et al.
Journal of chromatography. A, 1023(1), 93-104 (2004-02-06)
A new multi-residue method for determination of pesticide residues in a wide variety of fruit and vegetables, using the National Food Administration (NFA) ethyl acetate extraction and determination by means of LC-MS/MS, is presented. The method includes pesticides normally detected
Perspectives for the biotechnological production of ethyl acetate by yeasts.
Loser C, et al.
Applied Microbiology and Biotechnology, 98(12), 5397-5415 (2014)
Manganese oxide OMS-2 as an effective catalyst for total oxidation of ethyl acetate.
Gandhe AR, et al.
Applied Catalysis. B, Environmental, 72(1), 129-135 (2007)

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