223476

Kaliumbisulfat

reagent grade

• Synonym(e): Kaliumhydrogensulfat
• Lineare Formel: KHSO₄
• CAS-Nummer: 7646-93-7
• Molekulargewicht: 136.17
• EG-Nummer: 231-594-1
• MDL-Nummer: MFCD00011404
• UNSPSC-Code: 12352302
• eCl@ss: 38030413
• PubChem Substanz-ID: 329752310
• NACRES: NA.21

Eigenschaften

• Qualität: reagent grade
• Qualitätsniveau: 200
• Form: powder or crystals
• Konzentration: 35.0-37.0% H₂SO₄ (titration)
• mp (Schmelzpunkt): 214 °C (lit.)
• Säurezahl: 35‑37%(as H₂SO₄)
• Dichte: 2.32 g/mL at 25 °C (lit.)
• SMILES String: [K+].OS([O-])(=O)=O
• InChI: 1S/K.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+1;/p-1
• InChIKey: CHKVPAROMQMJNQ-UHFFFAOYSA-M

Beschreibung

Allgemeine Beschreibung

Potassium bisulfate is a water soluble inorganic salt mainly used as a preservative, as a flux and also in the manufacture of fertilizers.

Potassium bisulfate is an inorganic potassium salt. On heating it from 300 to 700°C, it transforms to molten form and the reactions occurring in this transition have been investigated by Raman spectra. Its electrical conductance values have been evaluated (T = 0-700C, Pressure = upto 4000bars).

Anwendung

Potassium bisulfate (Potassium hydrogen sulfate) may be employed as a catalyst in the synthesis of butyl paraben and methyl cinnamate. It may also be used for the gravimetric estimation of beryllium in beryl.

Potassium bisulfate may be used:

• As a catalyst for the preparation of butyl paraben from p-hydroxybenzoic acid and n-butyl alcohol.
• As a promoter for the synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives via Biginelli reaction in ethylene glycol.
• As an acid catalyst for the synthesis of ethyl tert-butyl ether (ETBE) from ethanol and tert-butyl alcohol via reactive distillation.
• As a dehydrating agent for the synthesis of pyruvic acid from tartaric acid.

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H314,H335
• P-Sätze: P260 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 8A - Combustible corrosive hazardous materials
• WGK: WGK 1
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable