82270

1,2-Dichlorpropan

99%

• Synonym(e): Propylendichlorid
• Lineare Formel: CH₃CHClCH₂Cl
• CAS-Nummer: 78-87-5
• Molekulargewicht: 112.99
• Beilstein: 1718880
• EG-Nummer: 201-152-2
• MDL-Nummer: MFCD00000868
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 329769241
• NACRES: NA.22

Eigenschaften

• Dampfdichte: 3.89 (vs air)
• Qualitätsniveau: 100
• Dampfdruck: 40 mmHg ( 19.4 °C)
• Assay: 99%
• Form: liquid
• Selbstzündungstemp.: 1035 °F
• Expl.-Gr.: 14.5 %
• Brechungsindex: n20/D 1.439 (lit.); n20/D 1.439
• bp: 95-96 °C (lit.)
• mp (Schmelzpunkt): −100 °C (lit.)
• Dichte: 1.156 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: chloro
• SMILES String: CC(Cl)CCl
• InChI: 1S/C3H6Cl2/c1-3(5)2-4/h3H,2H2,1H3
• InChIKey: KNKRKFALVUDBJE-UHFFFAOYSA-N

Beschreibung

Anwendung

1,2-Dichloropropane can be used as a building block to synthesize:

•  2-Ylidene-1,3-dithiolane derivatives via one-pot reaction with carbon disulfide and active methylene compounds in the presence of sodium ethylate.      
• β-Chloropropylsulfurs by controllable dechloro-coupling reaction with thiols.      
• Thiazolidine and 1,3-thiazinane derivatives via [3+2] and [3+3] annulation reaction with β-ketothioamides in the presence of phosphonium ylide as a catalyst.

Sicherheitshinweise

• Piktogramme: GHS02,GHS06,GHS08
• Signalwort: Danger
• H-Sätze: H225,H302,H331,H350
• P-Sätze: P202 - P210 - P233 - P301 + P312 - P304 + P340 + P311 - P308 + P313
• Gefahreneinstufungen: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Flam. Liq. 2
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 59.0 °F - closed cup
• Flammpunkt (°C): 15.0 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter