ALD00238

Sodium trifluoropropylsulfinate

• Synonym(e): Baran TFPS-Na Reagent
• Empirische Formel (Hill-System): C₃H₄F₃NaO₂S
• CAS-Nummer: 1263377-91-8
• Molekulargewicht: 184.11
• MDL-Nummer: MFCD18379709
• UNSPSC-Code: 12352001
• PubChem Substanz-ID: 329772647
• NACRES: NA.22

Eigenschaften

• Form: solid
• Qualitätsniveau: 100
• Eignung der Reaktion: reaction type: C-C Bond Formation; reagent type: catalyst; reaction type: C-H Activation
• SMILES String: O=S(CCC(F)(F)F)[O-].[Na+]
• InChI: 1S/C3H5F3O2S.Na/c4-3(5,6)1-2-9(7)8;/h1-2H2,(H,7,8);/q;+1/p-1
• InChIKey: DVCULODZLVVYHT-UHFFFAOYSA-M

Beschreibung

Anwendung

The following Baran Sulfinate is a part of a toolbox of diversification reagents, which are ideal for the late-stage functionalization of nitrogen-containing heterocycles. The regioselectivity can be effectively tuned by modification of the pH and solvent selection.

Radical-Based Regioselective C–H Functionalization of Electron-Deficient Heteroarenes: Scope; Tunability; and Predictability

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable