692794

(S,S)-DACH-phenyl Trost-Ligand

95%

• Synonym(e): (1S,2S)-(–)-1,2-Diaminocyclohexan-N,N′-bis-(2-diphenylphosphinobenzoyl)
• Empirische Formel (Hill-System): C₄₄H₄₀N₂O₂P₂
• CAS-Nummer: 169689-05-8
• Molekulargewicht: 690.75
• MDL-Nummer: MFCD01631274
• UNSPSC-Code: 12352002
• PubChem Substanz-ID: 329761528
• NACRES: NA.06

Eigenschaften

• Qualitätsniveau: 100
• Assay: 95%
• Form: solid
• Optische Aktivität: [α]20/D -134°, c = 1 in methanol
• mp (Schmelzpunkt): 136-142 °C
• Funktionelle Gruppe: amide; phosphine
• SMILES String: O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
• InChI: 1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m0/s1
• InChIKey: AXMSEDAJMGFTLR-ZAQUEYBZSA-N

Beschreibung

Anwendung

Trost Ligands for Asymmetric Allylic Alkylation

Asymmetric allylic alkylation ligand.

Verpackung

Bottomless glass bottle. Contents are inside inserted fused cone.

Rechtliche Hinweise

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only. US Patent 5739396 applies.

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)