677264

(4-(N,N-Dimethylamino)-phenyl)-di-tert.-butylphosphin

95%

• Synonym(e): A-^taPhos
• Empirische Formel (Hill-System): C₁₆H₂₈NP
• CAS-Nummer: 932710-63-9
• Molekulargewicht: 265.37
• MDL-Nummer: MFCD09265102
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 24885360
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 95%
• Form: solid
• Eignung der Reaktion: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reagent type: ligand; reaction type: Cross Couplings
• mp (Schmelzpunkt): 57-61 °C
• Funktionelle Gruppe: phosphine
• SMILES String: CN(C)c1ccc(cc1)P(C(C)(C)C)C(C)(C)C
• InChI: 1S/C16H28NP/c1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8/h9-12H,1-8H3
• InChIKey: IQTHEAQKKVAXGV-UHFFFAOYSA-N

Beschreibung

Anwendung

Ligand used to prepare a palladium dichloride catalyst (678740) on treatment with PdCl₂(COD). The catalyst effectively cross-couples aryl boronic acids with heteroaryl chlorides.

Sicherheitshinweise

• Piktogramme: GHS05
• Signalwort: Danger
• H-Sätze: H314
• P-Sätze: P280 - P305 + P351 + P338 - P310
• Gefahreneinstufungen: Skin Corr. 1B
• Lagerklassenschlüssel: 8B - Non-combustible, corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable