673013

2-Benzyloxyphenylmagnesiumbromid -Lösung

1.0 M in THF

• Empirische Formel (Hill-System): C₁₃H₁₁BrMgO
• CAS-Nummer: 328000-16-4
• Molekulargewicht: 287.43
• MDL-Nummer: MFCD08705262
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24885138
• NACRES: NA.22

Eigenschaften

• Eignung der Reaktion: reaction type: Grignard Reaction
• Qualitätsniveau: 100
• Konzentration: 1.0 M in THF
• Dichte: 1.047 g/mL at 25 °C
• Funktionelle Gruppe: phenyl
• SMILES String: Br[Mg]c1ccccc1OCc2ccccc2
• InChI: 1S/C13H11O.BrH.Mg/c1-3-7-12(8-4-1)11-14-13-9-5-2-6-10-13;;/h1-9H,11H2;1H;/q;;+1/p-1
• InChIKey: VELKJPFZDYXBDE-UHFFFAOYSA-M

Beschreibung

Anwendung

2-Benzyloxyphenylmagnesium bromide can be used:

• As a substrate in the iron-catalyzed coupling reaction of aryl Grignard reagents with unprotected bromophenols.
• As a substrate in the cross-coupling of Grignard reagents using diaryl titanates and ferric chloride.
• In one of the key synthetic steps for the total synthesis of an antibiotic caboxamycin.

Sicherheitshinweise

• Piktogramme: GHS02,GHS08,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H225,H302,H314,H335,H351
• P-Sätze: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• Gefahreneinstufungen: Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014,EUH019
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): -4.0 - 5.0 °F - closed cup
• Flammpunkt (°C): -20 - -15 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter