593230

Phenyllithium -Lösung

1.9 M in dibutyl ether

• Synonym(e): PhLi
• Empirische Formel (Hill-System): C₆H₅Li
• CAS-Nummer: 591-51-5
• Molekulargewicht: 84.04
• Beilstein: 506502
• MDL-Nummer: MFCD00014254
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24881428
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Konzentration: 1.9 M in dibutyl ether
• Dichte: 0.835 g/mL at 25 °C
• Lagertemp.: 2-8°C
• SMILES String: [Li]c1ccccc1
• InChI: 1S/C6H5.Li/c1-2-4-6-5-3-1;/h1-5H;
• InChIKey: NHKJPPKXDNZFBJ-UHFFFAOYSA-N

Beschreibung

Anwendung

Phenyllithium solution can be used to synthesize:

• 1-Acetyl-1′-diphenylphosphinoferrocene from ferrocenophane.
• Ethyl 2-acetylimino-1-benzyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from ethyl 1-benzyl-6-bromo-2-imino-1,2-dihydroquinoline-3-carboxylate.
• Ethyl 2-amino-1-benzoyl-6-bromo-4-phenyl-1,4-dihydroquinoline-3-carboxylate from (E)-ethyl 2-(acetylimino)-1-benzoyl-6-bromo-1,2-dihydroquinoline-3-carboxylate.

Sicherheitshinweise

• Piktogramme: GHS02,GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H226,H314,H335,H412
• P-Sätze: P210 - P233 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.2 - Pyrophoric and self-heating hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 77.0 °F - closed cup
• Flammpunkt (°C): 25 °C - closed cup