520160

Shi-Epoxidierung-Diketalkatalysator

98%

• Synonym(e): 1,2:4,5-Di-O-isopropyliden-β-D-erythro-2,3-hexodiulo-2,6-pyranose
• Empirische Formel (Hill-System): C₁₂H₁₈O₆
• CAS-Nummer: 18422-53-2
• Molekulargewicht: 258.27
• MDL-Nummer: MFCD11865369
• UNSPSC-Code: 12352005
• PubChem Substanz-ID: 24874093
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 98%
• Optische Aktivität: [α]20/D −120.9°, c = 1 in chloroform
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp (Schmelzpunkt): 102-104 °C (lit.)
• Funktionelle Gruppe: ether; ketal; ketone
• Grünere Alternativprodukt-Kategorie: , Aligned
• SMILES String: CC1(C)O[C@@H]2CO[C@]3(COC(C)(C)O3)C(=O)[C@@H]2O1
• InChI: 1S/C12H18O6/c1-10(2)15-6-12(18-10)9(13)8-7(5-14-12)16-11(3,4)17-8/h7-8H,5-6H2,1-4H3/t7-,8-,12+/m1/s1
• InChIKey: IVWWFWFVSWOTLP-RWYTXXIDSA-N

Beschreibung

Allgemeine Beschreibung

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

This organocatalyst is able to epoxidize trans alkenes and certain cis alkenes with good to excellent yields and selectivities.

Highly selective and active organocatalyst for the asymmetric epoxidation of alkenes with hydrogen peroxide. Green epoxidation catalyst of choice according to Glaxo-Smith-Kline's reagent guide.

An Efficient Catalytic Asymmetric Epoxidation Method

Use of an Iridium-Catalyzed Redox-Neutral Alcohol-Amine Coupling on Kilogram Scale for the Synthesis of a GlyT1 Inhibitor

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)