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3-Pyridinboronsäure
≥95.0%
Synonym(e):
3-Pyridinylborsäure
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About This Item
Empirische Formel (Hill-System):
C5H6BNO2
CAS-Nummer:
Molekulargewicht:
122.92
MDL-Nummer:
UNSPSC-Code:
12352103
PubChem Substanz-ID:
NACRES:
NA.22
Empfohlene Produkte
Qualitätsniveau
Assay
≥95.0%
Form
solid
mp (Schmelzpunkt)
>300 °C (lit.)
SMILES String
OB(O)c1cccnc1
InChI
1S/C5H6BNO2/c8-6(9)5-2-1-3-7-4-5/h1-4,8-9H
InChIKey
ABMYEXAYWZJVOV-UHFFFAOYSA-N
Verwandte Kategorien
Anwendung
3-Pyridinylboronic acid can be used as a reagent for:
It can also be used to prepare:
- Phosphine-free Suzuki-Miyaura cross-coupling reactions.
- Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulation.
- N-arylation using copper acetylacetonate catalyst.
- Copper-mediated cyanation and regioselective cyanation of electron-rich benzenes.
It can also be used to prepare:
- New linear poly(phenylpyridyl) chains by Suzuki coupling.
- Oligopyridyl foldamers as mimics of a-helix twist.
- Many highly significant therapeutic enzymatic and kinase inhibitors and receptor antagonists.
- Pyridine substituted pyridinium N-(2′-azinyl)aminides by reacting with dibromo pyridinium aminides via Suzuki coupling reaction.
Sonstige Hinweise
Contains varying amounts of anhydride
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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The synthesis and biological activity of a new series of LpxC inhibitors represented by pyridone methylsulfone hydroxamate 2a is presented. Members of this series have improved solubility and free fraction when compared to compounds in the previously described biphenyl methylsulfone
Brian C Shook et al.
Journal of medicinal chemistry, 55(3), 1402-1417 (2012-01-14)
The design and characterization of two, dual adenosine A(2A)/A(1) receptor antagonists in several animal models of Parkinson's disease is described. Compound 1 was previously reported as a potential treatment for Parkinson's disease. Further characterization of 1 revealed that it was
Regioselective Suzuki coupling on pyridinium N-(3,5-dibromoheteroar-2-yl)aminides
M. Jose R, et al.
Tetrahedron Letters, 47, 36, 6457-6460 (2006)
Jana Sopkova-de Oliveira Santos et al.
Journal of chemical information and modeling, 52(2), 429-439 (2011-12-27)
Protein-protein interactions are central to many biological processes, from intracellular communication to cytoskeleton assembly, and therefore represent an important class of targets for new therapeutics. The most common secondary structure in natural proteins is an α-helix. Small molecules seem to
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