404926

Vanadium(V)-oxytriisopropoxid

• Synonym(e): Triisopropoxyvanadium(V)-oxid, Vanadium(V)-trisisopropoxid-oxid
• Lineare Formel: OV(OCH(CH₃)₂)₃
• CAS-Nummer: 5588-84-1
• Molekulargewicht: 244.20
• EG-Nummer: 226-997-4
• MDL-Nummer: MFCD00015017
• UNSPSC-Code: 12352103
• PubChem Substanz-ID: 24865281
• NACRES: NA.23

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Zusammensetzung: V, 20.3-21.4% titration (by potassium permanganate)
• Eignung der Reaktion: core: vanadium; reagent type: catalyst
• Brechungsindex: n20/D 1.479 (lit.)
• bp: 80-82 °C/2 mmHg (lit.)
• Dichte: 1.035 g/mL at 25 °C (lit.)
• SMILES String: CC(C)O[V](=O)(OC(C)C)OC(C)C
• InChI: 1S/3C3H7O.O.V/c3*1-3(2)4;;/h3*3H,1-2H3;;/q3*-1;;+3
• InChIKey: DSGGJXAUQHKOGQ-UHFFFAOYSA-N

Beschreibung

Anwendung

Building block for a series of neutral oxovanadium complexes containing both ethoxide and acetylacetonate ligands the complexes have potential biological relevance as well as uses in catalysis.

Asymmetric Transfer Hydrogenation

Sicherheitshinweise

• Piktogramme: GHS02,GHS07
• Signalwort: Warning
• H-Sätze: H226,H315,H319,H335
• P-Sätze: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 3
• Flammpunkt (°F): 113.0 °F - closed cup
• Flammpunkt (°C): 45 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter