384305

6-Hydroxypyridin-2-carbonsäure

95%

• Synonym(e): 6-Hydroxy-picolinsäure, 6-Hydroxy-pyridin-2-carbonsäure
• Empirische Formel (Hill-System): C₆H₅NO₃
• CAS-Nummer: 19621-92-2
• Molekulargewicht: 139.11
• Beilstein: 115842
• MDL-Nummer: MFCD00192220
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24863659
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 95%
• Form: solid
• mp (Schmelzpunkt): 270 °C (dec.) (lit.)
• Funktionelle Gruppe: carboxylic acid
• SMILES String: OC(=O)c1cccc(O)n1
• InChI: 1S/C6H5NO3/c8-5-3-1-2-4(7-5)6(9)10/h1-3H,(H,7,8)(H,9,10)
• InChIKey: VRCWSYYXUCKEED-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

6-Hydroxypyridine-2-carboxylic acid (6HPA, 6-Hydroxypicolinic acid) is a picolinic acid derivative. It has been reported to exhibit enol-keto tautomerism. It is a chelating ligand exhibiting potential complexing ability (via N,O-chelation or N,O,O-chelation). Intramolecular proton transfer (IPT) in tautomeric forms of 6HPA has been investigated by density functional theory (DFT) calculations.

Anwendung

6-Hydroxypyridine-2-carboxylic acid may be used in the preparation of ruthenium(II) complex, [RuH(CO)(6-OH-py-2-COO)(PPh₃)₂].

Sicherheitshinweise

• Piktogramme: GHS07
• Signalwort: Warning
• H-Sätze: H315,H319,H335
• P-Sätze: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: dust mask type N95 (US), Eyeshields, Gloves