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Merck

359009

Sigma-Aldrich

Cer(IV)-sulfat

Synonym(e):

Ceric sulfate

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About This Item

Lineare Formel:
Ce(SO4)2
CAS-Nummer:
Molekulargewicht:
332.24
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12161600
PubChem Substanz-ID:
NACRES:
NA.22

Form

powder

Qualitätsniveau

Eignung der Reaktion

core: cerium
reagent type: catalyst

Dichte

3.01 g/mL at 25 °C (lit.)

SMILES String

[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O

InChI

1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4

InChIKey

VZDYWEUILIUIDF-UHFFFAOYSA-J

Anwendung

Cerium(IV) sulfate can be used to catalyze:
  • Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
  • Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
  • Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.

Reactant for:
  • Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions

  • Oxidizing agent

Sonstige Hinweise

may contain excess sulfate

Piktogramme

CorrosionEnvironment

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Lagerklassenschlüssel

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves


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A simple and accurate kinetic method for the determination of propranolol has been developed. Cerium(IV) sulphate (0.5 M) is used to oxidize propranolol in 2 M sulphuric acid at room temperature to the ketone form that absorbs light at a

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