357537

Pentamethylcyclopentadienyliridium(III)-chlorid, Dimer

96%

• Synonym(e): di-μ-chlorodichlorobis[(1,2,3,4,5-η)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-iridium
• Empirische Formel (Hill-System): C₂₀H₃₀Cl₄Ir₂
• CAS-Nummer: 12354-84-6
• Molekulargewicht: 796.70
• MDL-Nummer: MFCD00075435
• UNSPSC-Code: 12161600
• PubChem Substanz-ID: 24861924
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 96%
• Form: solid
• Eignung der Reaktion: core: iridium; reagent type: catalyst
• Grünere Alternativprodukt-Eigenschaften: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Grünere Alternativprodukt-Kategorie: Aligned,
• SMILES String: Cl[Ir]Cl.Cl[Ir]Cl.C[C]1[C](C)[C](C)[C](C)[C]1C.C[C]2[C](C)[C](C)[C](C)[C]2C
• InChI: 1S/2C10H15.4ClH.2Ir/c2*1-6-7(2)9(4)10(5)8(6)3;;;;;;/h2*1-5H3;4*1H;;/q;;;;;;2*+2/p-4
• InChIKey: JDOHSXHCQARCAW-UHFFFAOYSA-J

Beschreibung

Allgemeine Beschreibung

Pentamethylcyclopentadienyliridium(III) chloride, dimer is utilized as a catalyst in cross-coupling and dimerization reactions.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Anwendung

Catalyst for greener amine synthesis from amines and alcohols by hydrogen-borrowing. Precursor to cooperative metal-Bronsted acid catalyst for greener reductive amination using hydrogen gas.

Metal-Brønsted Acid Cooperative Catalysis for Asymmetric Reductive Amination

Development of GSK's reagent guides – embedding sustainability into reagent selection

Sicherheitshinweise

• Lagerklassenschlüssel: 11 - Combustible Solids
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable
• Persönliche Schutzausrüstung: Eyeshields, Gloves, type N95 (US)