294861
1-Chloradamantan
98%
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Alle Fotos(2)
About This Item
Empirische Formel (Hill-System):
C10H15Cl
CAS-Nummer:
Molekulargewicht:
170.68
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22
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Qualitätsniveau
Assay
98%
Form
solid
mp (Schmelzpunkt)
165-166 °C (lit.)
Funktionelle Gruppe
chloro
SMILES String
ClC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C10H15Cl/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-
InChIKey
OZNXTQSXSHODFR-CHIWXEEVSA-N
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Allgemeine Beschreibung
An unusual zwitterionic diradical intermediate complex was generated during the photoinduced electron-transfer substitution reaction between 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass.
Anwendung
1-Chloroadamantane was employed as precursor for the synthesis of perfluoroadmantane derivatives via aerosol direct fluorination.
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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John B Miller et al.
Journal of the American Chemical Society, 126(40), 12742-12743 (2004-10-08)
An unusual zwitterionic diradical intermediate complex R*...X-...HR'B*+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR'B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25
Xue Li et al.
Journal of pharmaceutical sciences, 106(1), 395-401 (2016-11-07)
Supramolecular cyclodextrin-based nanoparticles (CD-NPs) mediated by host-guest interactions have gained increased popularity because of their "green" and simple preparation procedure, as well as their versatility in terms of inclusion of active molecules. Herein, we showed that original CD-NPs of around
Aerosol fluorination of 1-chloroadamantane, 2-chloroadamantane, and methyl 1-adamantylacetate: a novel synthetic approach to 1-and 2-substituted hydryl-, methyl-, and (difluoromethyl-F-adamantanes.
Adcock JL, et al.
The Journal of Organic Chemistry, 57(17), 4749-4752 (1992)
Elena L Gromnitskaya et al.
Physical chemistry chemical physics : PCCP, 23(3), 2349-2354 (2021-01-16)
We present a comparative ultrasonic study of the elastic properties of adamantane and 1-chloroadamantane at high pressure (up to 1.4 GPa) and different temperatures (77-293 K) and at order-disorder transitions. The ultrasonic method provides complementary pictures of the order-disorder transitions
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