179043

Boran-N,N-diethylanilin-Komplex

• Synonym(e): (N,N-Diethylaniline)trihydroboron, Diethylphenylamine-borane, NSC 239123
• Lineare Formel: C₆H₅N(C₂H₅)₂·BH₃
• CAS-Nummer: 13289-97-9
• Molekulargewicht: 163.07
• EG-Nummer: 236-305-2
• MDL-Nummer: MFCD00013187
• UNSPSC-Code: 12352116
• PubChem Substanz-ID: 24850794
• NACRES: NA.22

Eigenschaften

• Form: liquid
• Qualitätsniveau: 200
• Eignung der Reaktion: reagent type: reductant
• mp (Schmelzpunkt): −30-−27 °C (lit.)
• Dichte: 0.917 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: amine
• SMILES String: B.CCN(CC)c1ccccc1
• InChI: 1S/C10H15N.BH3/c1-3-11(4-2)10-8-6-5-7-9-10;/h5-9H,3-4H2,1-2H3;1H3
• InChIKey: YPWBYWNNJVSNPQ-UHFFFAOYSA-N

Beschreibung

Anwendung

Reactant for:

• Diastereoselective reduction of prochiral enone intermediates
• Borylation of aryl halides
• Reductions of ketones, acids, esters, amides, and nitriles
• Investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones

Reactant for synthesis of:

• Chromanol derivatives as CETP inhibitors for the treatment of cardiovascular disease
• Allylic alcohols via enantioselective reductions
• Pinacolboranes for one-pot synthesis of unsymmetrical biaryls

Sicherheitshinweise

• Piktogramme: GHS02
• Signalwort: Danger
• H-Sätze: H225,H261
• P-Sätze: P210 - P223 - P231 + P232 - P233 - P240 - P241
• Gefahreneinstufungen: Flam. Liq. 2 - Water-react 2
• Zusätzliche Gefahrenhinweise: EUH014
• Lagerklassenschlüssel: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3
• Flammpunkt (°F): 69.8 °F - closed cup
• Flammpunkt (°C): 21 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter