157910

Methylbromacetat

97%

• Synonym(e): 2-Bromoacetic acid methyl ester, Bromoacetic acid methyl ester, Carbomethoxymethyl bromide, Methyl α-bromoacetate, Methyl 2-bromoacetate, Methyl 2-bromoethanoate
• Lineare Formel: BrCH₂COOCH₃
• CAS-Nummer: 96-32-2
• Molekulargewicht: 152.97
• Beilstein: 506256
• EG-Nummer: 202-499-2
• MDL-Nummer: MFCD00000189
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24849708
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 97%
• Form: liquid
• Brechungsindex: n20/D 1.458 (lit.)
• bp: 51-52 °C/15 mmHg (lit.)
• Dichte: 1.616 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: bromo; ester
• SMILES String: COC(=O)CBr
• InChI: 1S/C3H5BrO2/c1-6-3(5)2-4/h2H2,1H3
• InChIKey: YDCHPLOFQATIDS-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Methyl bromoacetate is an α-bromo ester. Reactions of the methyl bromoacetate with conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) yields alkylated carbene complexes.

Anwendung

Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes.

Sicherheitshinweise

• Piktogramme: GHS06,GHS05
• Signalwort: Danger
• H-Sätze: H301,H314,H317
• P-Sätze: P261 - P272 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1C - Skin Sens. 1
• Lagerklassenschlüssel: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): 147.2 °F - closed cup
• Flammpunkt (°C): 64 °C - closed cup
• Persönliche Schutzausrüstung: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter