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1,3,5-Tribrombenzol
98%
Synonym(e):
1,3,5-Tribromobenzene
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About This Item
Empfohlene Produkte
Qualitätsniveau
Assay
98%
Form
powder
bp
271 °C (lit.)
mp (Schmelzpunkt)
117-121 °C (lit.)
Funktionelle Gruppe
bromo
SMILES String
Brc1cc(Br)cc(Br)c1
InChI
1S/C6H3Br3/c7-4-1-5(8)3-6(9)2-4/h1-3H
InChIKey
YWDUZLFWHVQCHY-UHFFFAOYSA-N
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Allgemeine Beschreibung
- 1,3,5-Tribromobenzene(TBB) acts as internal standard during derivatization step in determination of cyanide in human plasma and urine by gas chromatography-mass spectrometry.
- TBB forms molecular complexes of 1:2 stoichiometry with [60]-and [70] fullerenes.
- TBB reacts with perfluoroalkenylzinc reagent in the presence of Pd(Ph3)4 catalyst to yield a novel trifunctional monomer 1,3,5-tris(α, β, β-trifluorovinyl)benzene.
H-Sätze
Gefahreneinstufungen
Aquatic Chronic 4
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
Persönliche Schutzausrüstung
Eyeshields, Gloves, type N95 (US)
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Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 877(27), 3054-3058 (2009-09-08)
Cyanide (CN) is a powerful poison and rapidly toxic agent. Because of its wide availability and high toxicity, quantification of CN in blood and urine is frequently required in clinical and forensic practice. We present a sensitive and less time
Chemical communications (Cambridge, England), (20)(20), 2596-2597 (2003-11-05)
The reaction of the perfluoroalkenylzinc reagent, CF2=CFZnBr, with 1,3,5-tribromobenzene in the presence of a catalytic amount of Pd(Ph3)4 yielded a novel trifunctional monomer 1,3,5-tris(alpha,beta,beta-trifluorovinyl)benzene (1).
Journal of forensic sciences, 33(1), 217-222 (1988-01-01)
A sensitive analysis of sulfide in blood was established, using an extractive alkylation technique. Pentafluorobenzyl bromide was used as the alkylating agent, tetradecyldimethylbenzylammonium chloride as the phase-transfer catalyst, and potassium dihydrogenphosphate as the buffer to suppress the formation of sulfide.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 62(1-3), 66-70 (2005-11-01)
By UV-vis spectrophotometric method it has been shown that 1,3,5-tribromobenzene (TBB) forms molecular complexes of 1:2 stoichiometry with [60]- and [70]fullerenes. An isosbestic point could be detected in case of the [70]fullerene complex. The formation constant of the [60]fullerene complex
Nucleic acids symposium series, (44)(44), 125-126 (2003-08-09)
We have designed a new type of a DNA dendrimer which has rigid branched structure. The branching molecule was prepared from 1,3,5-tribromobenzene. The dendrimer unit, in which three oligonucleotide-chains, two molecules of T15 and one molecule of A15, linked to
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