108995

Methylthioglycolat

95%

• Synonym(e): Methyl-thioglykolat
• Lineare Formel: HSCH₂CO₂CH₃
• CAS-Nummer: 2365-48-2
• Molekulargewicht: 106.14
• Beilstein: 506259
• EG-Nummer: 219-121-7
• MDL-Nummer: MFCD00004873
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24846848
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 200
• Assay: 95%
• Eignung der Reaktion: reagent type: ligand; reaction type: [1,2]-Wittig Rearrangement
• Brechungsindex: n20/D 1.466 (lit.)
• bp: 42-43 °C/10 mmHg (lit.)
• Dichte: 1.187 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: ester; thiol
• SMILES String: COC(=O)CS
• InChI: 1S/C3H6O2S/c1-5-3(4)2-6/h6H,2H2,1H3
• InChIKey: MKIJJIMOAABWGF-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Methyl thioglycolate reacts with nonprotein component of the antitumor antibiotic neocarzinostatin to form 1:1 adduct. It reacts with isothiocyanate to form Rhodanine.

Anwendung

Methyl thioglycolate was used in the preparation of:

• 3-carbomethoxy-4- oxotetrahydrothiopyran, 2- and 4-carbomethoxy-3-oxotetrahydrothiophene
• methyl thioglycolate and aminoethanethiol conjugated gold nanorods.

Thiol Organocatalyst used in conjunction with visible light photocatalysis to affect the direct arylation of benzylic ether C-H bonds

A General Strategy for Organocatalytic Activation of C–H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Sicherheitshinweise

• Piktogramme: GHS02,GHS06
• Signalwort: Danger
• H-Sätze: H226,H301,H315,H319,H332,H335
• P-Sätze: P210 - P233 - P301 + P310 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338
• Gefahreneinstufungen: Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 3 - Flammable liquids
• WGK: WGK 1
• Flammpunkt (°F): 132.8 °F - closed cup
• Flammpunkt (°C): 56 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter