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Sigma-Aldrich

Poly(ethylene glycol) diamine

average MN 10,000, cross-linking reagent carboxyl reactive, amine

Synonym(s):

Poly(ethylene glycol) bis(amine), Polyethylene glycol, O,O′-Bis(2-aminoethyl)polyethylene glycol, Diaminopolyethylene glycol, PEG-diamine, Polyoxyethylene bis(amine)

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About This Item

Linear Formula:
H2N(CH2CH2O)nCH2CH2NH2
CAS Number:
24991-53-5
MDL number:
MFCD00132004
UNSPSC Code:
12162002
NACRES:
NA.23

product name

Poly(ethylene glycol) diamine, average Mn 10,000

form

powder or solid (or chunk(s))

Quality Level

100

mol wt

average Mn 10,000

reaction suitability

reagent type: cross-linking reagent
reactivity: carboxyl reactive

mp

56-60 °C

Ω-end

amine

α-end

amine

polymer architecture

shape: linear
functionality: homobifunctional

InChI

1S/C6H16N2O2/c7-1-3-9-5-6-10-4-2-8/h1-8H2

InChI key

IWBOPFCKHIJFMS-UHFFFAOYSA-N

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Application

Polymer for preparing enzyme conjugates soluble in organic solvents†; promising drug carrier†

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6408
MKCT5032
MKCS3786
MKCR2454
MKCM6821

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Malar A. Azagarsamy, et al.
Material Matters, 7 (2012)
Naoki Yamamoto et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 13(2), 613-625 (2006-09-16)
This paper describes synthesis of asparagine-linked sialylglycopeptides. The typical feature of our strategy for the synthesis of a sialylglycopeptide is to employ undecadisialyloligosaccharyl Fmoc-asparagine (Fmoc-Asn(CHO)-OH) 1 without protecting groups on its hydroxyl groups except for the benzyl ester of the
Cara E Humphrey et al.
Journal of the American Chemical Society, 125(46), 13952-13953 (2003-11-13)
The lipase-catalyzed kinetic resolution of (R/S)-3-phenylbutyric acid 2 using solid-supported cyclohexane-1,3-dione (CHD) 6 is described. In each case the predominant enantiomer observed, after cleavage from the resin, was (R)-(-)-3-phenylbutyric acid (R)-2 (ee > 99%) rather than the expected (S)-enantiomer of
Alessandra Basso et al.
Chemical communications (Cambridge, England), (11)(11), 1296-1297 (2003-06-18)
PEGA supports functionalised with permanent charges show superior swelling properties in aqueous media when compared to neutral PEGA; a novel positively charged PEGA resin significantly improves penicillin G amidase (PGA) catalysed biotransformation on solid support, by favouring accessibility of the
Takahiko Matsushita et al.
The Journal of organic chemistry, 71(8), 3051-3063 (2006-04-08)
A MUC1-related glycopeptide having five core-2 hexasaccharide branches (C330H527N46O207, MW = 8450.9) was synthesized by a new strategy using a combination of microwave-assisted solid-phase synthesis (MA-SPGS) and enzymatic sugar elongation. Synthesis of a key glycopeptide intermediate was best achieved in
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