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643653

Sigma-Aldrich

Aluminosilicate, mesostructured

MCM-41 (hexagonal)

Synonym(s):

MCM-41 molecular sieves

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About This Item

Linear Formula:
(SiO2)x(Al2O3)y
CAS Number:
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

form

powder

composition

aluminum, ~3%

surface area

900-1100 m2/g , BET

unit cell size

4.5-4.8 nm

pore size

0.8-1.1 cm3/g pore volume
2-4 nm pore size

application(s)

battery manufacturing

SMILES string

O=[Si]=O.O=[Al]O[Al]=O

InChI

1S/2Al.O2Si.3O/c;;1-3-2;;;

InChI key

HNPSIPDUKPIQMN-UHFFFAOYSA-N

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General description

Aluminosilicate, mesostructured (Al-MSU) is an analog of hexagonal MCM-41 that can be assembled by zeolite seeds. It is hydrothermally stable and strongly acidic, which makes it useful in catalysis and adsorption technology.

Application

Al-MSU can be used as an adsorbent in the formation of hybrid membranes for fuel cell applications. It can also be used as a catalyst for biomass pyrolysis and production of aromatic amine antioxidants.

Formula variant

(SiO2)0.9875(Al2O3)0.0125­­·xH2O

Storage Class Code

11 - Combustible Solids

WGK

nwg

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Aluminosilicate mesostructures with improved acidity and hydrothermal stability
Liu Y and Pinnavaia TJ
Journal of Materials Chemistry, 12(11), 3179-3190 (2002)
Mesostructured aluminosilicate alkylation catalysts for the production of aromatic amine antioxidants
Liu Y, et al.
J. Catal., 225(2), 381-387 (2004)
Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds
Liu Y, et al.
Journal of the American Chemical Society, 122(36), 8791-8792 (2000)
Mesostructured-aluminosilicate-Nafion hybrid membranes for direct methanol fuel cells
Meenakshi S, et al.
Electrochimica Acta, 89(11), 35-44 (2013)
Hydrothermally stable mesoporous aluminosilicates (MSU-S) assembled from zeolite seeds as catalysts for biomass pyrolysis
Triantafyllidis KS, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 99(1-2), 132-139 (2007)

Articles

Mesoporous Materials include a range of high surface area porous silicates with applications in gas adsorption, drug delivery, diagnostics and catalysis.

Mesoporous materials self-assemble from sol-gel precursors and amphiphiles, forming versatile structures for various applications.

Mesoporous materials self-assemble from sol-gel precursors and amphiphiles, forming versatile structures for various applications.

Mesoporous materials self-assemble from sol-gel precursors and amphiphiles, forming versatile structures for various applications.

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