494070
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine
90%
Synonym(s):
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine
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About This Item
Empirical Formula (Hill Notation):
C15H9Br2N3
CAS Number:
Molecular Weight:
391.06
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Assay
90%
mp
257-263 °C (lit.)
functional group
bromo
SMILES string
Brc1cccc(n1)-c2cccc(n2)-c3cccc(Br)n3
InChI
1S/C15H9Br2N3/c16-14-8-2-6-12(19-14)10-4-1-5-11(18-10)13-7-3-9-15(17)20-13/h1-9H
InChI key
PYMBATDYUCQLBC-UHFFFAOYSA-N
General description
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine is a substituted terpyridine that can be synthesized from 2,6-dibromopyridine.
Application
6,6′′-Dibromo-2,2′:6′,2′′-terpyridine may be used in the synthesis of a novel disubstituted terpyridine ligand.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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A Novel One-Pot Synthesis of 6,6''-Dibromo-2,2':6'2''-terpyridine.
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ChemInform, 26(50) (1995)
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A new pentadentate quinoline-pyridine ligand and its iron (1), cobalt (2) and nickel (3) complexes have been synthesized and characterized. The iron complex exhibits excellent photocatalytic activity towards CO2-to-CO conversion with a TON(CO) of 544 and a selectivity of 99.3%
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A new disubstituted terpyridine ligand and the corresponding tri-copper(II) complex have been prepared and characterised. The binding affinity and binding mode of this tri-copper complex (as well as the previously reported mono- and di-copper analogues) towards duplex DNA were determined
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