450219
Silver hexafluorophosphate
99.99% trace metals basis
Synonym(s):
Silver hexafluorophosphate (AgPF6 ), Silver(1+) hexafluorophosphate
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About This Item
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Quality Level
Assay
99.99% trace metals basis
form
powder
reaction suitability
reagent type: catalyst
core: silver
impurities
≤150.0 ppm Trace Metal Analysis
mp
102 °C (dec.) (lit.)
SMILES string
[Ag+].F[P-](F)(F)(F)(F)F
InChI
1S/Ag.F6P/c;1-7(2,3,4,5)6/q+1;-1
InChI key
SCQBROMTFBBDHF-UHFFFAOYSA-N
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Application
Used in the development of new catalyst systems for stereoselective addition of alcohols to alkynes. Acidic catalyst for the synthesis of unsymmetrical sulfides and vinyl fluorides. Used to prepare silver 3,3′-dicyanodiphenylacetylene coordination networks for study of the effect of ligands on network structure toward the goal of engineering novel materials.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Synthetic Communications, 22, 1461-1461 (1992)
Chemistry Letters (Jpn), 727-727 (1996)
Chemistry Letters (Jpn), 1-1 (1993)
Inorganic chemistry, 36(14), 2960-2968 (1997-07-02)
Coordination networks of 3,3'-dicyanodiphenylacetylene (3,3'-DCPA, 1) with silver(I) salts characterized by single-crystal X-ray analysis are described. Network topology is found to depend on both the counterion and solvent employed during crystallization. The conformation adopted by the ligand varies between planar
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