334545
Potassium gold(III) chloride
98%
Synonym(s):
Potassium tetrachloroaurate(III), Gold potassium chloride
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About This Item
Linear Formula:
KAuCl4
CAS Number:
Molecular Weight:
377.88
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
98%
form
powder
solubility
H2O: soluble
alcohol: soluble
ethanol: soluble
SMILES string
[K+].Cl[Au-](Cl)(Cl)Cl
InChI
1S/Au.4ClH.K/h;4*1H;/q+3;;;;;+1/p-4
InChI key
JMONCQYBAMKVQQ-UHFFFAOYSA-J
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General description
The yellow crystals of potassium gold chloride are soluble in water. 1,2
Application
Key raw material for synthesis of new gold(III) dithiolate complexes for luminescence studies or possible uses as photosensitizers or photocatalysts.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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M. Adnan Mansour et al.
Inorganic chemistry, 37(18), 4625-4632 (2001-10-24)
Two Au(III) dithiolate complexes, [Au(dbbpy)(tdt)]PF(6) and Au(eta(2)-C,N-ppy)(tdt), (dbbpy = 4,4'-di-tert-butyl-2,2'-bipyridine; tdt = 3,4-toluenedithiolate; ppy = C-deprotonated 2-phenylpyridine), have been prepared and structurally characterized by X-ray crystallography. The complexes have low-energy absorption bands that exhibit mild solvatochromism (lambda(max) = 444 nm
Andrew R Garcia et al.
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Fluorescent insulin fibrils gold nanoclusters (Au NCs) have been synthesized through the reduction of gold by human insulin in fibrillated form. Likewise, nanocluster formation has been regulated by insulin, working as a protein-based template. Environment- and surface-controlled experiments have shown
Xiaokong Liu et al.
Langmuir : the ACS journal of surfaces and colloids, 28(38), 13720-13726 (2012-09-08)
In this report, we demonstrate a rapid and simple seeded growth method for synthesizing monodisperse, quasi-spherical, citrate-stabilized Au nanoparticles (Au NPs) via H(2)O(2) reduction of HAuCl(4). Au NPs with diameter ranging from 30 to 230 nm can be synthesized by
Sergey S Zalesskiy et al.
Journal of the American Chemical Society, 135(9), 3550-3559 (2013-01-02)
Soluble gold precatalysts, aimed for homogeneous catalysis, under certain conditions may form nanoparticles, which dramatically change the mechanism and initiate different chemistry. The present study addresses the question of designing gold catalysts, taking into account possible interconversions and contamination at
Xianqing Tian et al.
Talanta, 93, 79-85 (2012-04-10)
Graphene decorated with gold nanoparticles (AuNPs-β-CD-Gra) has been synthesized by in situ thermal reduction of graphene oxide and HAuCl(4) with β-cyclodextrin (β-CD) under alkaline condition. The AuNPs-β-CD-Gra product was well characterized by infrared spectroscopy, X-ray powder diffraction, scanning electron microscopy
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