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C3654

Sigma-Aldrich

Ammonium cerium(IV) nitrate

≥98% (titration)

Synonym(s):

Ceric ammonium nitrate

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About This Item

Linear Formula:
Ce(NH4)2(NO3)6
CAS Number:
16774-21-3
Molecular Weight:
548.22
EC Number:
240-827-6
MDL number:
MFCD00151121
UNSPSC Code:
12352302
PubChem Substance ID:
329775041
NACRES:
NA.55
grade:
for analytical purposes
form:
powder or crystals
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grade

for analytical purposes

Assay

≥98% (titration)

form

powder or crystals

reaction suitability

reagent type: oxidant

pH

0.61 (20 °C, 111.11 g/L)

SMILES string

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI key

WIBGOERAEYJBOT-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW3421
MKCV6388
MKCS1750
MKCN1224
MKCJ2717

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Jingliang Jiao et al.
Organic letters, 9(7), 1323-1326 (2007-03-06)
[structure: see text]. The oxidation of selected anions (N3-, SCN-, I-, and Br-) by ceric ammonium nitrate (CAN) in the presence of substituted cyclopropyl alcohols provides a novel approach to beta-functionalized ketones. The protocol has a number of advantages including
Mazaahir Kidwai et al.
Chemical & pharmaceutical bulletin, 58(10), 1320-1323 (2010-10-12)
An environment friendly method for the synthesis of 2-oxo/thioxooctahydroquinazolin-5-one derivatives has been devised using Ceric ammonium nitrate (CAN) as catalyst and polyethylene glycol (PEG) as solvent. The cytotoxic effect of these compounds was studied on U87 human glioma cells, compounds
Vijay Nair et al.
Accounts of chemical research, 37(1), 21-30 (2004-01-21)
Cerium(IV) ammonium nitrate (CAN) has recently emerged as a versatile reagent for oxidative electron transfer; the overwhelming number of reports serve as a testimony to the unparalleled utility of CAN in a variety of transformations of synthetic importance. Our recent
Amit H Haviv et al.
Journal of the American Chemical Society, 132(36), 12519-12521 (2010-08-26)
The high-power ultrasonic irradiation of preformed magnetite (Fe(3)O(4)) nanoparticles in the presence of monoelectronic Ce-containing ceric ammonium nitrate [Ce(IV)(NH(4))(2)(NO(3))(6)] oxidant in MeCOMe afforded hydrophilic 50 nm-sized colloidal, highly stable maghemite (gamma-Fe(2)O(3)) nanoparticles. An "inorganic" Ce atom doping of the NP
Kuppusamy Sujatha et al.
Bioorganic & medicinal chemistry letters, 19(15), 4501-4503 (2009-06-02)
An efficient and eco-friendly method for the synthesis of 4,4'-(arylmethylene)bis(1H-pyrazol-5-ols) has been accomplished by tandem Knoevenagel-Michael reaction of two equivalents of 5-methyl-2-phenyl-2,4-dihydro-3H-pyrazol-3-one with various aromatic aldehydes catalyzed by ceric ammonium nitrate (CAN) in water. All the synthesized compounds 3a-j were
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