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195804

Sigma-Aldrich

Ethylenediamine dihydrochloride

98%

Synonym(s):

1,2-Diaminoethane dihydrochloride

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About This Item

Linear Formula:
NH2CH2CH2NH2 · 2HCl
CAS Number:
333-18-6
Molecular Weight:
133.02
Beilstein:
3665235
EC Number:
206-369-6
MDL number:
MFCD00012524
UNSPSC Code:
12352100
PubChem Substance ID:
24851714
NACRES:
NA.22
Pricing and availability is not currently available.

Quality Level

200

Assay

98%

form

solid

mp

>300 °C (lit.)

solubility

water: soluble 100 mg/mL, clear, colorless to very faintly yellow

functional group

amine

SMILES string

Cl[H].Cl[H].NCCN

InChI

1S/C2H8N2.2ClH/c3-1-2-4;;/h1-4H2;2*1H

InChI key

OHHBFEVZJLBKEH-UHFFFAOYSA-N

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Application

Ethylenediamine dihydrochloride was used in modified ethylenediamine condensation method for fluorimetric determination of catecholamines[1]. It was used to investigate the luminescence properties of complexes of EuIII and TbIII with ethylenediamine[2]. It was used in the synthesis of 1,3,5-tris(4,5-dihydro-1H-imidazol-2-yl)benzene[3].

Pictograms

Health hazardExclamation mark
GHS08,GHS07

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCW9077
MKCV1498
MKCS3840
MKCN7853
MKCN1662

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Self-assembled organogels based on two-component system.
Nam SR, et al.
Tetrahedron, 64(46), 10531-10537 (2008)
Modified ethylenediamine condensation method and its application in the analysis of catecholamines by ion-exchange chromatography.
Seki T.
Journal of Chromatography A, 155(2), 415-420 (1978)
Luminescence spectroscopic study of europium (III) and terbium (III) with ethylenediamine in dimethyl sulfoxide.
Wang Z, et al.
J. Chem. Soc., Dalton Trans., 18, 2791-2796 (1993)
Ana Carolina M S Dias et al.
Biosensors & bioelectronics, 44, 216-221 (2013-02-23)
An immunosensor for the non-structural protein 1 (NS1) of the dengue virus based on carbon nanotube-screen printed electrodes (CNT-SPE) was successfully developed. A homogeneous mixture containing carboxylated carbon nanotubes was dispersed in carbon ink to prepare a screen printed working
Shinichi Mochizuki et al.
Biochimica et biophysica acta, 1828(2), 412-418 (2012-10-25)
Gene therapy is expected to treat various incurable diseases including viral infections, autoimmune disorders, and cancers. Cationic lipids (CL) have been used as carriers of therapeutic DNAs for gene therapy because they can form a complex with DNA and such
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Questions

1–3 of 3 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. could you please inform me about the disassociation constant pKa value of Ethylenediamine dihydrochloride?

    1 answer

    1. The dissociation constant for this compound is not available. This value may be determined empirically from titration. This calculation can be modeled through the Henderson-Hasselbalch equation. Please see the link below to review:
      https://byjus.com/chemistry/how-to-calculate-pka/#3

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