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Merck
모든 사진(1)

주요 문서

695076

Sigma-Aldrich

Formic acid

Formic acid

ACS reagent, ≥96%

로그인조직 및 계약 가격 보기

크기 선택

100 ML
₩75,922
500 ML
₩135,807

₩75,922


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

크기 선택

보기 변경
100 ML
₩75,922
500 ML
₩135,807

About This Item

Linear Formula:
HCOOH
CAS Number:
Molecular Weight:
46.03
Beilstein:
1209246
EC Number:
MDL number:
UNSPSC 코드:
12352106
PubChem Substance ID:
NACRES:
NA.21
Grade:
ACS reagent
pH:
2.2 (20 °C, 2.2 g/L)

₩75,922


예상 입고일2025년 1월 31일세부사항


벌크 견적 요청

Grade

ACS reagent

Quality Level

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

분석

≥96%

양식

liquid

autoignition temp.

1004 °F

expl. lim.

57 %

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 2.2 g/L)

bp

100-101 °C (lit.)

mp

8.2-8.4 °C (lit.)

solubility

water: miscible

density

1.22 g/mL at 25 °C (lit.)

음이온 미량물

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.003%
sulfite (SO32-): passes test

양이온 미량물

Fe: ≤0.001%
NH4+: ≤0.005%
heavy metals (as Pb): ≤0.001%

응용 분야

sample preparation

SMILES string

OC=O

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

유사한 제품을 찾으십니까? 방문 제품 비교 안내

일반 설명

Formic acid is a simple carboxylic acid produced by the hydrolysis of methyl formate or formamide or from its salts. It is primarily used in dyeing, textile, leather, rubber, chemical, and pharmaceutical industries.

애플리케이션

Formic acid can be used as a reagent in the:
  • Co-Nx-catalyzed one-pot reductive amination of carbonyl compounds with nitro compounds to synthesize secondary amines.
  • Photoreduction of polycyclic and heterocyclic nitro arenes to corresponding amines.
  • Pd-catalyzed chemoselective hydrogenation of olefins to saturated hydrocarbons.

픽토그램

FlameSkull and crossbonesCorrosion

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

보충제 위험성

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

121.1 °F - closed cup

Flash Point (°C)

49.5 °C - closed cup


가장 최신 버전 중 하나를 선택하세요:

시험 성적서(COA)

Lot/Batch Number

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특정 버전이 필요한 경우 로트 번호나 배치 번호로 특정 인증서를 찾을 수 있습니다.

이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Electron momentum spectroscopy of formic acid.
Nixon KL, et al.
Chemical Physics Letters, 474(1), 23-27 (2009)
Direct formic acid fuel cells.
Rice C, et al.
Journal of Power Sources, 111(1), 83-89 (2002)
Photodissociation of formic acid.
Su H, et al.
J. Chem. Phys. , 113(5), 1891-1897 (2000)
The crystal structure of formic acid.
Holtzberg F, et al.
Acta Crystallographica, 6(2), 127-130 (1953)
Switchgrass pretreatment and hydrolysis using low concentrations of formic acid.
Marzialetti T, et al.
Journal of Chemical Technology and Biotechnology, 86(5), 706-713 (2011)

문서

Rapid trypsin digest kit yields reliable results in less than 2 hours for mass spectrometry analysis.

Using an Ascentis® Express F5 HPLC column, this study separates 11 β-agonists in pork by LC-MS/MS in under 8 minutes with excellent recovery and precision.

질문

1–3 / 3 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How to make 0.2M formic acid solution?

    1 답변
    1. Assuming a 96% purity, to prepare 100mL of a 0.2 M solution, slowly add 0.786 mL of your stock solution to 25 mL deionized water. Adjust the final volume of solution to 100 mL with deionized water.

      To prepare 500mL of a 0.2 M solution, slowly add 3.930 mL of your stock solution to 125 mL deionized water. Adjust the final volume of solution to 500 mL with deionized water.

      See the link below to access the molarity calculator. Enter the desired volume, the lot specific product percentage, and the desired volume. Click the 'Calculate' button to get preparation instructions:
      https://www.sigmaaldrich.com/support/calculators-and-apps/molarity-calculator

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