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Merck
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주요 문서

255599

Sigma-Aldrich

Cobalt(II) chloride hexahydrate

ACS reagent, 98%

동의어(들):

Cobaltous chloride hexahydrate

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크기 선택

5 G
₩91,249
100 G
₩162,096
500 G
₩499,482

₩91,249


출고 가능일2025년 4월 16일세부사항


벌크 견적 요청

크기 선택

보기 변경
5 G
₩91,249
100 G
₩162,096
500 G
₩499,482

About This Item

Linear Formula:
CoCl2 · 6H2O
CAS Number:
Molecular Weight:
237.93
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21

₩91,249


출고 가능일2025년 4월 16일세부사항


벌크 견적 요청

Grade

ACS reagent

vapor pressure

40 mmHg ( 0 °C)

분석

98%
98.0-102.0% (ACS specification)

양식

powder, crystals or chunks

반응 적합성

reagent type: catalyst
core: cobalt

불순물

≤0.01% insolubles

음이온 미량물

nitrate (NO3-): ≤0.01%
sulfate (SO42-): ≤0.01%

양이온 미량물

Ca: ≤0.005%
Cu: ≤0.002%
Fe: ≤0.005%
K: ≤0.01%
Mg: ≤0.005%
Na: ≤0.05%
Ni: ≤0.1%
Zn: ≤0.03%

SMILES string

O.O.O.O.O.O.Cl[Co]Cl

InChI

1S/2ClH.Co.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2

InChI key

GFHNAMRJFCEERV-UHFFFAOYSA-L

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일반 설명

Cobalt(II) chloride hexahydrate, also known as cobaltous chloride hexahydrate, is a hydrated form of cobalt and chloride. It is a crystalline solid consisting of octahedral complexes, with the coordination polyhedron of the Co2+ ion including four H2O molecules and two Cl ions. It is highly soluble in water and is commonly used as a catalyst in various organic synthesis, such as during the synthesis of benzimidazole and biscoumarin derivatives. [1]

애플리케이션

Cobalt(II) chloride hexahydrate can be used as a catalyst for the:
  • Dioxygenation of styrenes with N-hydroxyphthalimide to synthesize corresponding alcohols and ketones.
  • Oxidative coupling of primary amines to imines.
  • Friedel-Crafts reaction between indoles and activated olefins to synthesize β-indolylketones.
  • Synthesis of β-enaminones and β-enamino esters.
  • Reaction of acyl chlorides with diselenides or disulfides to synthesize selenol and thiol esters.

신호어

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1

Storage Class Code

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


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시험 성적서(COA)

Lot/Batch Number

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이 제품을 이미 가지고 계십니까?

문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Cobalt (II) Chloride Hexahydrate as an Efficient and Inexpensive Catalyst for the Preparation of Biscoumarin Derivatives.
Mohammad Reza N, et al.
Advances in Chemistry, 1-6 null
A simple and convenient one-pot synthesis of benzimidazole derivatives using cobalt (II) chloride hexahydrate as catalyst
Abu K T, et al.
Synthetic Communications, 39, 2339-2346 (2009)
CoCl2. 6H2O crystal growth and its spectral characteristics
Diana Sergeevna M, et al.
Optical Materials, 144, 114339-114339 (2023)
Electronic absorption spectra of tetragonal and pseudotetragonal cobalt (II). II. Cobalt chloride hexahydrate and cobalt chloride hexahydrate-d12.
Ferguson J and Wood TE.
Inorganic Chemistry, 14(1), 184-189 (1975)
Water soluble nickel (0) and cobalt (0) nanoclusters stabilized by poly (4-styrenesulfonic acid-co-maleic acid): highly active, durable and cost effective catalysts in hydrogen generation from the hydrolysis of ammonia borane.
Metin O and Ozkar S.
International Journal of Hydrogen Energy, 36(2), 1424-1432 (2011)

질문

1–2 / 2 질문  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 답변
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 답변
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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