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Merck
모든 사진(4)

문서

213225

Sigma-Aldrich

Lithium bromide

ReagentPlus®, ≥99%

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About This Item

Linear Formula:
LiBr
CAS Number:
Molecular Weight:
86.85
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.21

vapor pressure

1 hPa ( 748 °C)

제품 라인

ReagentPlus®

분석

≥99%

형태

powder

pH

7 (20 °C, 10 g/L)

mp

550 °C (lit.)

SMILES string

[Li+].[Br-]

InChI

1S/BrH.Li/h1H;/q;+1/p-1

InChI key

AMXOYNBUYSYVKV-UHFFFAOYSA-M

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일반 설명

LiBr/Chlorotrimethylsilane reagent participates in the conversion of alcohols to bromides.

애플리케이션

Lithium bromide (LiBr) may be employed as a catalyst in the following studies:
  • Transformation of (aromatic- and α,β-unsaturated) aldehydes to dithioacetals via solvent-free dithioacetalization.
  • Synthesis of olefins via condensation reaction of carbonyl compounds with active methylene compounds.
  • Green synthesis of β-amino alcohols.
  • Chemo- and regioselective bromination of aromatic compounds was carried out by employing LiBr/ceric ammonium nitrate (CAN) reagent system (as a source of Br+ ion).

법적 정보

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
Redi-Dri is a trademark of Sigma-Aldrich Co. LLC

픽토그램

Exclamation mark

신호어

Warning

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable


시험 성적서(COA)

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문서 라이브러리 방문

이미 열람한 고객

Lithium bromide-catalyzed highly chemoselective and efficient dithioacetalization of α,β-unsaturated and aromatic aldehydes under solvent-free conditions.
Firouzabadi H, et al.
Synthesis, 58-60 (1999)
Lithium bromide as a new catalyst for carbon-carbon bond formation in the solid state.
Prajapati D, et al.
Journal of the Chemical Society. Perkin Transactions 1, 9, 959-960 (1996)
An efficient chemo and regioselective oxidative nuclear bromination of activated aromatic compounds using lithium bromide and ceric ammonium nitrate.
Roy SC, et al.
Tetrahedron Letters, 42(39), 6941-6942 (2001)
Lithium Bromide, an Inexpensive and Efficient Catalyst for Opening of Epoxide Rings by Amines at Room Temperature under Solvent-Free Condition.
Chakraborti AK, et al.
European Journal of Organic Chemistry, 2004(17), 3597-3600 (2004)
Eoghan M Cunnane et al.
ACS applied materials & interfaces, 12(24), 26955-26965 (2020-05-23)
Vascular tissue engineering is aimed at developing regenerative vascular grafts to restore tissue function by bypassing or replacing defective arterial segments with tubular biodegradable scaffolds. Scaffolds are often combined with stem or progenitor cells to prevent acute thrombosis and initiate

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