200085

Mercury(II) bromide

ACS reagent

• 동의어(들): Mercuric bromide
• Linear Formula: HgBr₂
• CAS Number: 7789-47-1
• Molecular Weight: 360.40
• EC Number: 232-169-3
• MDL number: MFCD00011040
• UNSPSC 코드: 12352302
• PubChem Substance ID: 329751967
• NACRES: NB.24

속성

• Grade: ACS reagent
• vapor pressure: 1 mmHg ( 136.5 °C)
• 양식: powder
• 반응 적합성: reagent type: catalyst; core: mercury
• 불순물: ≤0.05% insol. CH₃OH
• 산화 잔류물: ≤0.02%
• 색상: white to very faintly yellow
• bp: 322 °C (lit.)
• mp: 236 °C (lit.)
• 음이온 미량물: chloride (Cl^-): ≤0.25%
• SMILES string: Br[Hg]Br
• InChI: 1S/2BrH.Hg/h2*1H;/q;;+2/p-2
• InChI key: NGYIMTKLQULBOO-UHFFFAOYSA-L

설명

일반 설명

Mercury(II) bromide (HgBr₂) affords 1:1 adducts on reaction with N,N,N′,N′- tetramethyl-o-phenylenediamine. Single-crystal X-ray diffraction studies of these adducts have been reported.[1] It forms complexes by reacting with 3,12-dimethylbenzo[a]quinoxalino[2,3-c]phenazine ligand.[2]

애플리케이션

Mercury(II) bromide (HgBr₂) may be used in the preparation of mononuclear [Hg(L1)Br₂] and 1D polymer [Hg₂(L2)Br₄]_n [L1 = (N,N-diethyl,N′-(pyridin-2-yl)formylidene)ethane-1,2-diamine and L2 = (N,N-diethyl,N′-(pyridin-2-yl)benzylidene)ethane-1,2-diamine].[3] It may also be used as a promoter in the glycoslyation reaction of alcohols.[4]

안전성 정보

• 픽토그램: GHS06,GHS08,GHS09
• 신호어: Danger
• 유해 및 위험 성명서: H300 + H310 + H330,H373,H410
• 예방조치 성명서: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Hazard Classifications: Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Storage Class Code: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• WGK: WGK 3
• Flash Point (°F): Not applicable
• Flash Point (°C): Not applicable