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Merck
모든 사진(1)

문서

92330

Sigma-Aldrich

Trimethyl borate

purum, ≥99.0% (GC)

동의어(들):

Boric acid trimethyl ester, Methyl borate

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About This Item

Linear Formula:
B(OCH3)3
CAS Number:
Molecular Weight:
103.91
Beilstein:
1697939
EC Number:
MDL number:
UNSPSC 코드:
12352103
PubChem Substance ID:
NACRES:
NA.22

vapor density

3.59 (vs air)

Quality Level

grade

purum

분석

≥99.0% (GC)

형태

liquid

refractive index

n20/D 1.346 (lit.)
n20/D 1.358

bp

68-69 °C (lit.)

mp

−34 °C (lit.)

density

0.932 g/mL at 20 °C (lit.)

SMILES string

COB(OC)OC

InChI

1S/C3H9BO3/c1-5-4(6-2)7-3/h1-3H3

InChI key

WRECIMRULFAWHA-UHFFFAOYSA-N

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애플리케이션

Trimethyl borate (TMB) can be used:
  • For the synthesis of luminogens having triphenylamine core and tetraphenylethene peripheral moieties.
  • For the synthesis of ammonia borane and trialkylamine boranes.
  • In the reduction of carboxylic acids in the presence of borane-methyl sulfide.
  • As a reagent to crosslink phopshate complexes.
  • As a source of boron to synthesize boron nitride nanotubes by chemical vapor deposition (CVD) method.

픽토그램

FlameSkull and crossbonesHealth hazard

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - STOT SE 1

표적 기관

Eyes

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

12.2 °F - (own results)

Flash Point (°C)

-11 °C - (own results)

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리 방문

Organic synthesis using borane-methyl sulfide. II. Reduction of aromatic carboxylic acids in the presence of trimethyl borate.
Lane CF, et al.
The Journal of Organic Chemistry, 39(20), 3052-3054 (1974)
Changing the Behavior of Chromophores from Aggregation?Caused Quenching to Aggregation?Induced Emission: Development of Highly Efficient Light Emitters in the Solid State.
Yuan W Z, et al.
Advanced Materials, 22(19), 2159-2163 (2010)
Thermal-heating CVD synthesis of BN nanotubes from trimethyl borate and nitrogen gas.
Lin FH, et al.
Materials Chemistry and Physics, 107(1), 115-121 (2008)
R Meder et al.
Solid state nuclear magnetic resonance, 15(1), 69-72 (2000-07-21)
Boron-11 nuclear magnetic resonance imaging and spectroscopy have been used to characterise the nature and distribution of boron compounds after preservative treatment of radiata pine wood with trimethylborate (TMB). One day after treatment, 11B magnetic resonance imaging microscopy showed significant
One-Pot Synthesis of Ammonia-Borane and Trialkylamine-Boranes from Trimethyl Borate.
Veeraraghavan RP, et al.
Organic Letters, 14(24), 6119-6121 (2012)

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