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Merck
모든 사진(1)

문서

90161

Supelco

(2,2′)-Furildioxime

for spectrophotometric det. of Au(II), Co(II), Cu(II), Ni(II), Pd(II), Re(VII), U(VI), ≥97.0% (sum of isomers, HPLC)

동의어(들):

Bis(2-furyl)glyoxime

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About This Item

실험식(Hill 표기법):
C10H8N2O4
CAS Number:
Molecular Weight:
220.18
EC Number:
MDL number:
UNSPSC 코드:
12000000
PubChem Substance ID:
NACRES:
NA.21

설명

mixture of isomers

분석

≥97.0% (sum of isomers, HPLC)

형태

crystals

기술

UV/Vis spectroscopy: suitable

SMILES string

O\N=C(c1ccco1)\C(=N\O)c2ccco2

InChI

1S/C10H8N2O4/c13-11-9(7-3-1-5-15-7)10(12-14)8-4-2-6-16-8/h1-6,13-14H/b11-9+,12-10+

InChI key

RBOZTFPIXJBLPK-WGDLNXRISA-N

일반 설명

Oximes are selective reagents which react with limited number of metal ions. These form water-insoluble complexes extractable into organic solvents. Furildioxime, a gravimetric and colorimetric reagent for nickel, palladium, platinum and rhenium is prepared by the oximation of furil with hydroxyammonium chloride followed by aqueous recrystallisation using MacKair′s method.

애플리케이션

a-furildioxime [(2,2′)-Furildioxime] was used:
  • as neutral carrier in Calcium(II)-selective potentiometric sensor, selective electrode used for titration.
  • in the synthesis of ketenimines and bis(ketenimines).
  • in determination of palladium in water samples by rapid spectrophotometric analysis.

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H Mitani et al.
European journal of pharmacology, 411(1-2), 169-174 (2001-01-04)
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Najma Memon et al.
TheScientificWorldJournal, 2012, 418047-418047 (2012-06-02)
A very simple, selective, and fast flow injection spectrophotometeric method is developed for determination of nickel using furildioxime as complexing agent. Micellar solution of brij-35 is employed to solubilize the sparingly soluble complex of Ni-furildioxime in buffered aqueous system (pH-9.00).
Calcium (II)-selective potentiometric sensor based on a-furildioxime as neutral carrier.
Singh, Ashok Kumar, and Sameena Mehtab.
Sensors and Actuators B, Chemical, 123, 429-436 (2007)
Three-component reaction of alkyl isocyanides with acetylenic esters and pyridine-2-carboxaldoxime or a-furildioxime: Synthesis and dynamic NMR study of ketenimines and bis (ketenimines).
Baharfar, Robabeh, Leyla Jaafari, and Razieh Azimi.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 22, 943-946 (2011)
The furildioximes. Part I. The structure of the isomeric furildioximes.
Fryer, F. A., D. J. B. Galliford, and J. T. Yardley.
Analyst, 88, 188-190 (1963)

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